Technology Process of 2,2'-(cyclohexylmethylene)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
There total 15 articles about 2,2'-(cyclohexylmethylene)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
N′-(cyclohexylmethylene)-4-methylbenzenesulfonohydrazide;
With
sodium hydride;
In
toluene; mineral oil;
at 20 ℃;
for 1h;
Inert atmosphere;
Schlenk technique;
bis(pinacol)diborane;
In
toluene; mineral oil;
at 110 ℃;
for 12h;
Inert atmosphere;
Schlenk technique;
Sealed tube;
DOI:10.1021/ol403338s
- Guidance literature:
-
With
copper(l) iodide; lithium methanolate; triphenylphosphine;
In
N,N-dimethyl-formamide;
at 20 ℃;
for 24h;
Inert atmosphere;
Sealed tube;
DOI:10.1021/ja500029w
- Guidance literature:
-
5-(cyclohexylmethyl)-5,6-dihydrobenzo[e]pyrazolo[1,5-c][1,3,2]diazaborinine; bis(pinacol)diborane;
With
C9H12*Ir(3+)*3C6H13BO2(1-);
In
tetrahydrofuran;
at 80 ℃;
for 12h;
Inert atmosphere;
Sealed tube;
2,3-dimethyl-2,3-butane diol;
With
toluene-4-sulfonic acid;
In
tetrahydrofuran;
at 20 ℃;
for 5h;
Inert atmosphere;
Sealed tube;
DOI:10.1021/acs.orglett.9b02112
