((2R,3S,5S,6S)-3-(tert-butyldimethylsilyloxy)-6-((3E,5E)-7-(tert-butyldiphenylsilyloxy)-4,5-dimethylhepta-3,5-dienyl)-5-methyl-tetrahydro-2H-pyran-2-yl)methanol

Base Information

Chemical Name:((2R,3S,5S,6S)-3-(tert-butyldimethylsilyloxy)-6-((3E,5E)-7-(tert-butyldiphenylsilyloxy)-4,5-dimethylhepta-3,5-dienyl)-5-methyl-tetrahydro-2H-pyran-2-yl)methanol
CAS No.:1190239-54-3
Molecular Formula:C₃₈H₆₀O₄Si₂
Molecular Weight:637.063
Hs Code.:

((2R,3S,5S,6S)-3-(tert-butyldimethylsilyloxy)-6-((3E,5E)-7-(tert-butyldiphenylsilyloxy)-4,5-dimethylhepta-3,5-dienyl)-5-methyl-tetrahydro-2H-pyran-2-yl)methanol

Synonyms:((2R,3S,5S,6S)-3-(tert-butyldimethylsilyloxy)-6-((3E,5E)-7-(tert-butyldiphenylsilyloxy)-4,5-dimethylhepta-3,5-dienyl)-5-methyl-tetrahydro-2H-pyran-2-yl)methanol

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Chemical Property of ((2R,3S,5S,6S)-3-(tert-butyldimethylsilyloxy)-6-((3E,5E)-7-(tert-butyldiphenylsilyloxy)-4,5-dimethylhepta-3,5-dienyl)-5-methyl-tetrahydro-2H-pyran-2-yl)methanol

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Technology Process of ((2R,3S,5S,6S)-3-(tert-butyldimethylsilyloxy)-6-((3E,5E)-7-(tert-butyldiphenylsilyloxy)-4,5-dimethylhepta-3,5-dienyl)-5-methyl-tetrahydro-2H-pyran-2-yl)methanol

There total 1 articles about ((2R,3S,5S,6S)-3-(tert-butyldimethylsilyloxy)-6-((3E,5E)-7-(tert-butyldiphenylsilyloxy)-4,5-dimethylhepta-3,5-dienyl)-5-methyl-tetrahydro-2H-pyran-2-yl)methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 1245925-59-0
C₄₄H₇₄O₄Si₃

: 1190239-54-3
((2R,3S,5S,6S)-3-(tert-butyldimethylsilyloxy)-6-((3E,5E)-7-(tert-butyldiphenylsilyloxy)-4,5-dimethylhepta-3,5-dienyl)-5-methyl-tetrahydro-2H-pyran-2-yl)methanol

Guidance literature:: With methanol; In dichloromethane; at 0 ℃; for 1h;
DOI:10.1016/j.tet.2010.06.074

Reference yield: 90.0%

: 1190239-54-3
((2R,3S,5S,6S)-3-(tert-butyldimethylsilyloxy)-6-((3E,5E)-7-(tert-butyldiphenylsilyloxy)-4,5-dimethylhepta-3,5-dienyl)-5-methyl-tetrahydro-2H-pyran-2-yl)methanol

: 1245925-60-3
C₃₈H₅₉IO₃Si₂

Guidance literature:: With 1H-imidazole; iodine; triphenylphosphine; In toluene; at 20 ℃; for 0.833333h;
DOI:10.1016/j.tet.2010.06.074

Reference yield: 80.0%

: 1190239-54-3
((2R,3S,5S,6S)-3-(tert-butyldimethylsilyloxy)-6-((3E,5E)-7-(tert-butyldiphenylsilyloxy)-4,5-dimethylhepta-3,5-dienyl)-5-methyl-tetrahydro-2H-pyran-2-yl)methanol

: 1190239-60-1
((2E,4E)-7-((2S,3S,5S,6R)-6-(azidomethyl)-5-(tert-butyldimethylsilyloxy)-3-methyl-tetrahydro-2H-pyran-2-yl)-3,4-dimethylhepta-2,4-dienyloxy)(tert-butyl)diphenylsilane

Guidance literature:: ((2R,3S,5S,6S)-3-(tert-butyldimethylsilyloxy)-6-((3E,5E)-7-(tert-butyldiphenylsilyloxy)-4,5-dimethylhepta-3,5-dienyl)-5-methyl-tetrahydro-2H-pyran-2-yl)methanol; With di-isopropyl azodicarboxylate; triphenylphosphine; In tetrahydrofuran; at 0 ℃; for 0.0833333h; Inert atmosphere;

With diphenyl phosphoryl azide; In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere;
DOI:10.1021/ol901801h