(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-(1->6)-3,4,5-tri-O-benzyl-2-O-(2,3,4-tri-O-benzyl-6-O-palmitoyl-α-D-mannopyranosyl)-D-myo-inositol

Base Information

• Chemical Name: (2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-(1->6)-3,4,5-tri-O-benzyl-2-O-(2,3,4-tri-O-benzyl-6-O-palmitoyl-α-D-mannopyranosyl)-D-myo-inositol
• CAS No.: 737788-49-7
• Molecular Formula: C₁₀₄H₁₂₂O₁₇
• Molecular Weight: 1644.1

Synonyms:(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-(1->6)-3,4,5-tri-O-benzyl-2-O-(2,3,4-tri-O-benzyl-6-O-palmitoyl-α-D-mannopyranosyl)-D-myo-inositol

Chemical Property of (2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-(1->6)-3,4,5-tri-O-benzyl-2-O-(2,3,4-tri-O-benzyl-6-O-palmitoyl-α-D-mannopyranosyl)-D-myo-inositol

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Technology Process of (2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-(1->6)-3,4,5-tri-O-benzyl-2-O-(2,3,4-tri-O-benzyl-6-O-palmitoyl-α-D-mannopyranosyl)-D-myo-inositol

There total 3 articles about (2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-(1->6)-3,4,5-tri-O-benzyl-2-O-(2,3,4-tri-O-benzyl-6-O-palmitoyl-α-D-mannopyranosyl)-D-myo-inositol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

6-O-(2,3,4-tetra-O-benzyl-α-D-mannopyranosyl)-2-O-(2,3,4-tri-O-benzyl-α-D-mannopyranosyl)-3,4,5-tri-O-benzyl-D-myo-inositol (1391099-53-8) + n-hexadecanoyl chloride (112-67-4) → (2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-(1->6)-3,4,5-tri-O-benzyl-2-O-(2,3,4-tri-O-benzyl-6-O-palmitoyl-α-D-mannopyranosyl)-D-myo-inositol (737788-49-7)

Guidance literature:

With pyridine; In dichloromethane; at 30 ℃; for 2h; Molecular sieve;

DOI:10.1021/jo301189y

Reference yield: 81.0%

2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl-(1->6)-1-O-(4-methoxybenzyl)-3,4,5-tri-O-benzyl-2-O-(2,3,4-tri-O-benzyl-6-O-palmitoyl-α-D-mannopyranosyl)-D-myo-inositol (1191118-60-1) → (2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-(1->6)-3,4,5-tri-O-benzyl-2-O-(2,3,4-tri-O-benzyl-6-O-palmitoyl-α-D-mannopyranosyl)-D-myo-inositol (737788-49-7)

Guidance literature:

With trifluoroacetic acid; In dichloromethane; at 20 ℃; for 0.5h; Inert atmosphere;

DOI:10.1016/j.tetlet.2009.07.109

Reference yield: 51.0%

(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-(1->6)-1-O-allyl-3,4,5-tri-O-benzyl-2-O-(2,3,4-tri-O-benzyl-6-O-palmitoyl-α-D-mannopyranosyl)-D-myo-inositol → (2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-(1->6)-3,4,5-tri-O-benzyl-2-O-(2,3,4-tri-O-benzyl-6-O-palmitoyl-α-D-mannopyranosyl)-D-myo-inositol (737788-49-7)

Guidance literature:

With sodium acetate; acetic acid; palladium dichloride; at 20 ℃; for 6h; sonication;

DOI:10.1021/ja0565368

upstream raw materials:

2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl-(1->6)-1-O-(4-methoxybenzyl)-3,4,5-tri-O-benzyl-2-O-(2,3,4-tri-O-benzyl-6-O-palmitoyl-α-D-mannopyranosyl)-D-myo-inositol

6-O-(2,3,4-tetra-O-benzyl-α-D-mannopyranosyl)-2-O-(2,3,4-tri-O-benzyl-α-D-mannopyranosyl)-3,4,5-tri-O-benzyl-D-myo-inositol

n-hexadecanoyl chloride

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