2-(methoxycarbonyl)phenyl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-galactopyranoside

Base Information

• Chemical Name: 2-(methoxycarbonyl)phenyl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-galactopyranoside
• CAS No.: 382141-77-7
• Molecular Formula: C₄₂H₄₂O₇S
• Molecular Weight: 690.857

Synonyms:2-(methoxycarbonyl)phenyl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-galactopyranoside

Chemical Property of 2-(methoxycarbonyl)phenyl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-galactopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-(methoxycarbonyl)phenyl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-galactopyranoside

There total 6 articles about 2-(methoxycarbonyl)phenyl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-galactopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

benzyl bromide (100-39-0) + 2-(methoxycarbonyl)phenyl 1-thio-β-D-galactopyranoside (382141-84-6) → 2-(methoxycarbonyl)phenyl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-galactopyranoside (382141-77-7)

Guidance literature:

With sodium hydride; In N,N-dimethyl-formamide; for 16h;

DOI:10.1055/s-2001-16803

Reference yield: 91.0%

benzyl bromide (100-39-0) + (2R,3S,4S,5R,6S)-2-(acetoxymethyl)-6-((2-(methoxycarbonyl)phenyl)thio)tetrahydro-2H-pyran-3,4,5-triyl triacetate (382141-78-8) → 2-(methoxycarbonyl)phenyl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-galactopyranoside (382141-77-7)

Guidance literature:

With sodium hydride; In N,N-dimethyl-formamide; for 16h;

DOI:10.1016/S0008-6215(02)00093-9

Reference yield:

2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide (572-09-8) → 2-(methoxycarbonyl)phenyl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-galactopyranoside (382141-77-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 91 percent / K₂CO₃ / dimethylformamide / 2 h / 20 °C

2: 91 percent / NaH / dimethylformamide / 16 h

With sodium hydride; potassium carbonate; In N,N-dimethyl-formamide;

DOI:10.1016/S0008-6215(02)00093-9

upstream raw materials:

benzyl bromide

2-(methoxycarbonyl)phenyl 1-thio-β-D-galactopyranoside

(2R,3S,4S,5R,6S)-2-(acetoxymethyl)-6-((2-(methoxycarbonyl)phenyl)thio)tetrahydro-2H-pyran-3,4,5-triyl triacetate

2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide

Downstream raw materials:

(2R,3S,4S,5R,6S)-3,4,5-tris(benzyloxy)-2-((benzyloxy)methyl)-6-(((2R,3R,4S,5R,6S)-4,5-bis(benzyloxy)-2-((benzyloxy)methyl)-6-methoxytetrahydro-2H-pyran-3-yl)oxy)tetrahydro-2H-pyran

(2R,3S,4S,5R,6R)-3,4,5-tris(benzyloxy)-2-((benzyloxy)methyl)-6-(((2R,3R,4S,5R,6S)-4,5-bis(benzyloxy)-2-((benzyloxy)methyl)-6-methoxytetrahydro-2H-pyran-3-yl)oxy)tetrahydro-2H-pyran

(2S,3R,4R,5R,6R)-6-Benzyloxymethyl-2-(4-nitro-phenoxy)-5-((2R,3R,4S,5S,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3,4-diol

N-{4-[(2S,3R,4R,5R,6R)-3,4-Dihydroxy-6-hydroxymethyl-5-((2R,3R,4S,5R,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yloxy]-phenyl}-acrylamide

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 382141-77-7 2-(methoxycarbonyl)phenyl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-galactopyranoside

Send

Send

Metric Ton KG G Pound L ML

Send

Send