([PhNSiMe2CH2)2PPh]TaH)(μ-H)2(μ-η1:η2-NNSiH2Bu)(Ta[PhNSiMe2CH2)2PPh])

Base Information

• Chemical Name: ([PhNSiMe2CH2)2PPh]TaH)(μ-H)2(μ-η1:η2-NNSiH2Bu)(Ta[PhNSiMe2CH2)2PPh])
• CAS No.: 511522-50-2
• Molecular Formula: C₅₂H₇₆N₆P₂Si₅Ta₂
• Molecular Weight: 1349.49
• Mol file: 511522-50-2.mol

Synonyms:([PhNSiMe2CH2)2PPh]TaH)(μ-H)2(μ-η1:η2-NNSiH2Bu)(Ta[PhNSiMe2CH2)2PPh])

Chemical Property of ([PhNSiMe2CH2)2PPh]TaH)(μ-H)2(μ-η1:η2-NNSiH2Bu)(Ta[PhNSiMe2CH2)2PPh])

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ([PhNSiMe2CH2)2PPh]TaH)(μ-H)2(μ-η1:η2-NNSiH2Bu)(Ta[PhNSiMe2CH2)2PPh])

There total 1 articles about ([PhNSiMe2CH2)2PPh]TaH)(μ-H)2(μ-η1:η2-NNSiH2Bu)(Ta[PhNSiMe2CH2)2PPh]) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

n-butylsilane (1600-29-9) + ([PhP(CH2SiMe2NPh)2]Ta)2(μ–η1:η2-N2)(μ-H)2 → ([PhNSiMe2CH2)2PPh]TaH)(μ-H)2(μ-η1:η2-NNSiH2Bu)(Ta[PhNSiMe2CH2)2PPh]) (511522-50-2)

Guidance literature:

In toluene; under N2; Ta-contg. compd. was allowed to react with 1 equiv. of BuSiH3 at -60°C for 24 h; pptn. from toluene using hexanes or pentane;

DOI:10.1021/ja061508q

Reference yield: 92.0%

([PhNSiMe2CH2)2PPh]TaH)(μ-H)2(μ-η1:η2-NNSiH2Bu)(Ta[PhNSiMe2CH2)2PPh]) (511522-50-2) → ([PhNSiMe2CH2)2PPh]TaH)(μ-N)(μ-NSiH2Bu)(Ta[PhNSiMe2CH2)2PPh])

Guidance literature:

In toluene; byproducts: H2; under N2; Ta-contg. compd. was allowed to react with BuSiH3 at 15°C for 36 h; pptn. from toluene using hexanes or pentane;

DOI:10.1021/ja061508q

upstream raw materials:

n-butylsilane