dibutyl-[4-iodo-3-(4-triisopropylsilanyl-buta-1,3-diynyl)-phenyl]-amine

Base Information

Chemical Name:dibutyl-[4-iodo-3-(4-triisopropylsilanyl-buta-1,3-diynyl)-phenyl]-amine
CAS No.:367251-19-2
Molecular Formula:C₂₇H₄₂INSi
Molecular Weight:535.627
Hs Code.:

Synonyms:dibutyl-[4-iodo-3-(4-triisopropylsilanyl-buta-1,3-diynyl)-phenyl]-amine

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Chemical Property of dibutyl-[4-iodo-3-(4-triisopropylsilanyl-buta-1,3-diynyl)-phenyl]-amine

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Technology Process of dibutyl-[4-iodo-3-(4-triisopropylsilanyl-buta-1,3-diynyl)-phenyl]-amine

There total 3 articles about dibutyl-[4-iodo-3-(4-triisopropylsilanyl-buta-1,3-diynyl)-phenyl]-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 367251-07-8
dibutyl-[3-(4-triisopropylsilanyl-buta-1,3-diynyl)-phenyl]-amine

: 367251-19-2
dibutyl-[4-iodo-3-(4-triisopropylsilanyl-buta-1,3-diynyl)-phenyl]-amine

Guidance literature:: With N,N,N-trimethylbenzenemethanaminium dichloroiodate; calcium carbonate; In methanol; dichloromethane; at 22 ℃; for 3h;
DOI:10.1021/ol016414u

Reference yield:

: 149776-77-2
(Z)-(4-chlorobut-3-en-1-ynyl)triisopropylsilane

: 367251-19-2
dibutyl-[4-iodo-3-(4-triisopropylsilanyl-buta-1,3-diynyl)-phenyl]-amine

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-BuLi / tetrahydrofuran / 0.08 h / -78 °C

1.2: ZnBr₂ / tetrahydrofuran / 0.33 h / -78 - 0 °C

1.3: 76 percent / Pd(PPh₃)4 / tetrahydrofuran / 18 h / Heating

2.1: 75 percent / BnNMe₃ICl₂; CaCO₃ / methanol; CH₂Cl₂ / 3 h / 22 °C

With n-butyllithium; N,N,N-trimethylbenzenemethanaminium dichloroiodate; calcium carbonate; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1021/ol016414u

Reference yield:

: 248276-92-8
N,N-dibutyl-3-iodoaniline

: 367251-19-2
dibutyl-[4-iodo-3-(4-triisopropylsilanyl-buta-1,3-diynyl)-phenyl]-amine

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-BuLi / tetrahydrofuran / 0.08 h / -78 °C

1.2: ZnBr₂ / tetrahydrofuran / 0.33 h / -78 - 0 °C

1.3: 76 percent / Pd(PPh₃)4 / tetrahydrofuran / 18 h / Heating

2.1: 75 percent / BnNMe₃ICl₂; CaCO₃ / methanol; CH₂Cl₂ / 3 h / 22 °C

With n-butyllithium; N,N,N-trimethylbenzenemethanaminium dichloroiodate; calcium carbonate; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1021/ol016414u