(E)-3-[(2R,3S)-3-Butyl-2-((S)-toluene-4-sulfinyl)-oxiranyl]-prop-2-en-1-ol

Base Information

Chemical Name:(E)-3-[(2R,3S)-3-Butyl-2-((S)-toluene-4-sulfinyl)-oxiranyl]-prop-2-en-1-ol
CAS No.:211424-25-8
Molecular Formula:C₁₆H₂₂O₃S
Molecular Weight:294.415
Hs Code.:

Synonyms:(E)-3-[(2R,3S)-3-Butyl-2-((S)-toluene-4-sulfinyl)-oxiranyl]-prop-2-en-1-ol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (E)-3-[(2R,3S)-3-Butyl-2-((S)-toluene-4-sulfinyl)-oxiranyl]-prop-2-en-1-ol

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Technology Process of (E)-3-[(2R,3S)-3-Butyl-2-((S)-toluene-4-sulfinyl)-oxiranyl]-prop-2-en-1-ol

There total 3 articles about (E)-3-[(2R,3S)-3-Butyl-2-((S)-toluene-4-sulfinyl)-oxiranyl]-prop-2-en-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 211424-21-4
(2E,4Z)-4-((S)-Toluene-4-sulfinyl)-nona-2,4-dien-1-ol

: 211424-25-8
(E)-3-[(2R,3S)-3-Butyl-2-((S)-toluene-4-sulfinyl)-oxiranyl]-prop-2-en-1-ol

: (E)-3-[(2S,3R)-3-Butyl-2-(toluene-4-sulfonyl)-oxiranyl]-prop-2-en-1-ol

Guidance literature:: With tert.-butylhydroperoxide; sodium hydride; In tetrahydrofuran; at 0 ℃; for 1.5h; Yields of byproduct given;
DOI:10.1021/jo972358s

Reference yield:

: 211424-21-4
(2E,4Z)-4-((S)-Toluene-4-sulfinyl)-nona-2,4-dien-1-ol

: 211424-25-8
(E)-3-[(2R,3S)-3-Butyl-2-((S)-toluene-4-sulfinyl)-oxiranyl]-prop-2-en-1-ol

Guidance literature:: With tert.-butylhydroperoxide; sodium hydride; In tetrahydrofuran; at 0 ℃;
DOI:10.1016/j.tet.2004.06.092

Reference yield:

: 167690-79-1
1-((S)-(E)-1-Iodo-hex-1-ene-1-sulfinyl)-4-methyl-benzene

: 211424-25-8
(E)-3-[(2R,3S)-3-Butyl-2-((S)-toluene-4-sulfinyl)-oxiranyl]-prop-2-en-1-ol

Guidance literature:: Multi-step reaction with 2 steps

1: 80 percent / Ph₃As, 2,6-di-tert-butyl-4-methylphenol, Pd₂(dba)3*CHCl₃ / dimethylformamide / 2 h / Ambient temperature

2: 94 percent / t-BuOOH, NaH / tetrahydrofuran / 1.5 h / 0 °C

With tert.-butylhydroperoxide; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; triphenyl-arsane; 2,6-di-tert-butyl-4-methyl-phenol; sodium hydride; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1021/jo972358s