1,1-DIFLUORO-1,1A,6,10B-TETRAHYDRODIBENZO[A,E]CYCLOPROPA[C][7]ANNULEN-6-OL

Base Information

Chemical Name:1,1-DIFLUORO-1,1A,6,10B-TETRAHYDRODIBENZO[A,E]CYCLOPROPA[C][7]ANNULEN-6-OL
CAS No.:167155-76-2
Molecular Formula:C16H12 F2 O
Molecular Weight:258.267
Hs Code.:

Synonyms:1,1-DIFLUORO-1,1A,6,10B-TETRAHYDRODIBENZO[A,E]CYCLOPROPA[C][7]ANNULEN-6-OL

Suppliers and Price of 1,1-DIFLUORO-1,1A,6,10B-TETRAHYDRODIBENZO[A,E]CYCLOPROPA[C][7]ANNULEN-6-OL

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of 1,1-DIFLUORO-1,1A,6,10B-TETRAHYDRODIBENZO[A,E]CYCLOPROPA[C][7]ANNULEN-6-OL

Chemical Property:

PSA：20.23000
LogP:3.59800

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 1,1-DIFLUORO-1,1A,6,10B-TETRAHYDRODIBENZO[A,E]CYCLOPROPA[C][7]ANNULEN-6-OL

There total 2 articles about 1,1-DIFLUORO-1,1A,6,10B-TETRAHYDRODIBENZO[A,E]CYCLOPROPA[C][7]ANNULEN-6-OL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 167155-75-1
1,1-difluoro-1a,10b-dihydrodibenzo[a,e]cyclopropa[c]cyclohepten-6-one

: 167155-76-2
dibenzosuberenone

Guidance literature:: With sodium tetrahydroborate; In methanol;
DOI:10.1007/s00044-015-1497-3

Reference yield:

: 2222-33-5
dibenzosuberenon

: 167155-76-2
dibenzosuberenone

Guidance literature:: Multi-step reaction with 2 steps

1: Triethylene glycol dimethyl ether / 180 °C

2: sodium tetrahydroborate; methanol / 0 - 5 °C

With methanol; sodium tetrahydroborate; In Triethylene glycol dimethyl ether;
DOI:10.5935/0103-5053.20130275

Reference yield: 77.0%

: 167155-76-2
dibenzosuberenone

: 33575-83-6
2-(chloromethyl)-5-phenyl-1,3,4-oxadiazole

: 1,1-difluoro-1,1a,6,10b-tetrahydro-(1a,6,10b)-dibenzo[a,e]cyclopropa[c]cyclohepten-6-yloxymethyl-5-phenyl-[1,3,4]-oxadiazole

Guidance literature:: dibenzosuberenone; With sodium hydride; In N,N-dimethyl-formamide; at 0 - 5 ℃; for 0.25h;

2-(chloromethyl)-5-phenyl-1,3,4-oxadiazole; In N,N-dimethyl-formamide; at 0 - 5 ℃; for 1h;
DOI:10.5935/0103-5053.20130275