thiocarbonic acid O-{3-(tert-butyl-dimethyl-silanyloxymethyl)-2-[9-(4-methoxy-benzyloxy)-nonyl]-hexahydro-pyrrolo[1,2-b]isoxazol-4-yl} ester O-phenyl ester

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Chemical Name:thiocarbonic acid O-{3-(tert-butyl-dimethyl-silanyloxymethyl)-2-[9-(4-methoxy-benzyloxy)-nonyl]-hexahydro-pyrrolo[1,2-b]isoxazol-4-yl} ester O-phenyl ester
CAS No.:691006-86-7
Molecular Formula:C₃₇H₅₇NO₆SSi
Molecular Weight:672.014
Hs Code.:

thiocarbonic acid <i>O</i>-{3-(<i>tert</i>-butyl-dimethyl-silanyloxymethyl)-2-[9-(4-methoxy-benzyloxy)-nonyl]-hexahydro-pyrrolo[1,2-<i>b</i>]isoxazol-4-yl} ester <i>O</i>-phenyl ester

Synonyms:thiocarbonic acid O-{3-(tert-butyl-dimethyl-silanyloxymethyl)-2-[9-(4-methoxy-benzyloxy)-nonyl]-hexahydro-pyrrolo[1,2-b]isoxazol-4-yl} ester O-phenyl ester

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Chemical Property of thiocarbonic acid O-{3-(tert-butyl-dimethyl-silanyloxymethyl)-2-[9-(4-methoxy-benzyloxy)-nonyl]-hexahydro-pyrrolo[1,2-b]isoxazol-4-yl} ester O-phenyl ester

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Technology Process of thiocarbonic acid O-{3-(tert-butyl-dimethyl-silanyloxymethyl)-2-[9-(4-methoxy-benzyloxy)-nonyl]-hexahydro-pyrrolo[1,2-b]isoxazol-4-yl} ester O-phenyl ester

There total 6 articles about thiocarbonic acid O-{3-(tert-butyl-dimethyl-silanyloxymethyl)-2-[9-(4-methoxy-benzyloxy)-nonyl]-hexahydro-pyrrolo[1,2-b]isoxazol-4-yl} ester O-phenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 1005-56-7
phenylcarbonochloridothioate

: 691006-85-6
(2S,3S,3aR,4S)-3-(tert-Butyl-dimethyl-silanyloxymethyl)-2-[9-(4-methoxy-benzyloxy)-nonyl]-hexahydro-pyrrolo[1,2-b]isoxazol-4-ol

: 691006-86-7
thiocarbonic acid O-{3-(tert-butyl-dimethyl-silanyloxymethyl)-2-[9-(4-methoxy-benzyloxy)-nonyl]-hexahydro-pyrrolo[1,2-b]isoxazol-4-yl} ester O-phenyl ester

Guidance literature:: With pyridine; dmap;
DOI:10.1002/anie.200353200

Reference yield:

: (E)-12-(4-Methoxy-benzyloxy)-dodec-2-enoic acid ethyl ester

: 691006-86-7
thiocarbonic acid O-{3-(tert-butyl-dimethyl-silanyloxymethyl)-2-[9-(4-methoxy-benzyloxy)-nonyl]-hexahydro-pyrrolo[1,2-b]isoxazol-4-yl} ester O-phenyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: toluene / 19 h / 90 °C

2: LiAlH₄ / diethyl ether / 3 h / 0 °C

3: 6.63 g / CsF / ethanol / 13 h / 90 °C

4: 81 percent / pyridine / 19 h / 20 °C

5: 58 percent / DMAP; pyridine / 20 h / 20 °C

With pyridine; dmap; lithium aluminium tetrahydride; cesium fluoride; In diethyl ether; ethanol; toluene;
DOI:10.1002/chem.200500852

Reference yield:

: 874349-35-6
(2S,3R,3aR,4S)-2-[9-(4-Methoxy-benzyloxy)-nonyl]-4-triisopropylsilanyloxy-hexahydro-pyrrolo[1,2-b]isoxazole-3-carboxylic acid ethyl ester

: 691006-86-7
thiocarbonic acid O-{3-(tert-butyl-dimethyl-silanyloxymethyl)-2-[9-(4-methoxy-benzyloxy)-nonyl]-hexahydro-pyrrolo[1,2-b]isoxazol-4-yl} ester O-phenyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: LiAlH₄ / diethyl ether / 3 h / 0 °C

2: 6.63 g / CsF / ethanol / 13 h / 90 °C

3: 81 percent / pyridine / 19 h / 20 °C

4: 58 percent / DMAP; pyridine / 20 h / 20 °C

With pyridine; dmap; lithium aluminium tetrahydride; cesium fluoride; In diethyl ether; ethanol;
DOI:10.1002/chem.200500852