cis-1-methanesulfonyloxymethyl-2,2-dimethyl-6-methylene-3-<4-(2,4,6-trimethylbenzoyloxy)-3-methyl-2-E-buten-1-yl>-cyclohexane

Base Information

Chemical Name:cis-1-methanesulfonyloxymethyl-2,2-dimethyl-6-methylene-3-<4-(2,4,6-trimethylbenzoyloxy)-3-methyl-2-E-buten-1-yl>-cyclohexane
CAS No.:128806-69-9
Molecular Formula:C₂₆H₃₈O₅S
Molecular Weight:462.651
Hs Code.:

Synonyms:cis-1-methanesulfonyloxymethyl-2,2-dimethyl-6-methylene-3-<4-(2,4,6-trimethylbenzoyloxy)-3-methyl-2-E-buten-1-yl>-cyclohexane

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Chemical Property of cis-1-methanesulfonyloxymethyl-2,2-dimethyl-6-methylene-3-<4-(2,4,6-trimethylbenzoyloxy)-3-methyl-2-E-buten-1-yl>-cyclohexane

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Technology Process of cis-1-methanesulfonyloxymethyl-2,2-dimethyl-6-methylene-3-<4-(2,4,6-trimethylbenzoyloxy)-3-methyl-2-E-buten-1-yl>-cyclohexane

There total 6 articles about cis-1-methanesulfonyloxymethyl-2,2-dimethyl-6-methylene-3-<4-(2,4,6-trimethylbenzoyloxy)-3-methyl-2-E-buten-1-yl>-cyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 128806-67-7
γ-cis-1-hydroxymethyl-2,2-dimethyl-6-methylene-3-<4-(2,4,6-trimethylbenzoyloxy)-3-methyl-2-E-buten-1-yl>-cyclohexane

: 124-63-0
methanesulfonyl chloride

: 128806-69-9
cis-1-methanesulfonyloxymethyl-2,2-dimethyl-6-methylene-3-<4-(2,4,6-trimethylbenzoyloxy)-3-methyl-2-E-buten-1-yl>-cyclohexane

Guidance literature:: With triethylamine; In dichloromethane; at -10 ℃; Yield given;
DOI:10.1016/S0040-4020(01)85431-4

Reference yield:

: 105-87-3,8022-83-1
3,7-dimethyl-2E,6-octadien-1-yl acetate

: 128806-69-9
cis-1-methanesulfonyloxymethyl-2,2-dimethyl-6-methylene-3-<4-(2,4,6-trimethylbenzoyloxy)-3-methyl-2-E-buten-1-yl>-cyclohexane

Guidance literature:: Multi-step reaction with 4 steps

1: 8.4 percent / ZnCl₂ / nitromethane / 3 h / -20 °C

2: 90 percent / pyridine / CH₂Cl₂ / 24 h / 0 °C

3: 55 percent / 1.) POCl₃, pyridine, 2.) 1N NaOH / 1.) room temperature, overnight, 2.) ethanol, 0 deg C, 4 h

4: triethylamine / CH₂Cl₂ / -10 °C

With pyridine; sodium hydroxide; triethylamine; zinc(II) chloride; trichlorophosphate; In nitromethane; dichloromethane;
DOI:10.1016/S0040-4020(01)85431-4

Reference yield:

: 108287-02-1,108287-03-2,108287-04-3,108291-85-6
2-r-Acetoxymethyl-1,3,3-trimethyl-4-c(3-methyl-2-buten-1-yl)-1-t-cyclohexanol

: 128806-69-9
cis-1-methanesulfonyloxymethyl-2,2-dimethyl-6-methylene-3-<4-(2,4,6-trimethylbenzoyloxy)-3-methyl-2-E-buten-1-yl>-cyclohexane

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) SeO₂, t-BuOOH, salicylic acid, 2.) NaBH₄ / 1.) CH₂Cl₂, 30 h, room temperature, 2.) MeOH, 0 deg C, 30 min

2: 90 percent / pyridine / CH₂Cl₂ / 24 h / 0 °C

3: 55 percent / 1.) POCl₃, pyridine, 2.) 1N NaOH / 1.) room temperature, overnight, 2.) ethanol, 0 deg C, 4 h

4: triethylamine / CH₂Cl₂ / -10 °C

With pyridine; tert.-butylhydroperoxide; sodium hydroxide; sodium tetrahydroborate; selenium(IV) oxide; triethylamine; salicylic acid; trichlorophosphate; In dichloromethane;
DOI:10.1016/S0040-4020(01)85431-4