2,6-bis(2,6-bis((2,6-diisopropylphenyl)amino)methyl)pyridine

Base Information

• Chemical Name: 2,6-bis(2,6-bis((2,6-diisopropylphenyl)amino)methyl)pyridine
• CAS No.: 184640-73-1
• Molecular Formula: C₃₁H₄₃N₃
• Molecular Weight: 457.703
• Mol file: 184640-73-1.mol

Synonyms:2,6-bis(2,6-bis((2,6-diisopropylphenyl)amino)methyl)pyridine

Chemical Property of 2,6-bis(2,6-bis((2,6-diisopropylphenyl)amino)methyl)pyridine

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 2,6-bis(2,6-bis((2,6-diisopropylphenyl)amino)methyl)pyridine

There total 1 articles about 2,6-bis(2,6-bis((2,6-diisopropylphenyl)amino)methyl)pyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

2,6-diisopropylbenzenamine (24544-04-5) + 2,6-bis[(tosyloxy)methyl]pyridine (112633-26-8) → 2,6-bis(2,6-bis((2,6-diisopropylphenyl)amino)methyl)pyridine (184640-73-1)

Guidance literature:

2,6-diisopropylbenzenamine; With n-butyllithium; In tetrahydrofuran; at -78 - 20 ℃; Schlenk technique;

2,6-bis[(tosyloxy)methyl]pyridine; In tetrahydrofuran; at -78 ℃; for 16h; Schlenk technique;

DOI:10.1021/acscatal.6b03313

Reference yield: 99.0%

2,6-bis(2,6-bis((2,6-diisopropylphenyl)amino)methyl)pyridine (184640-73-1) + [scandium tris(trimethylsilylmethyl)(THF)2] (41705-65-1) → Sc(CH2SiMe3)(THF)(2,6-bis(((2,6-diisopropylphenyl)amino)methyl)pyridine(2-)) (507264-30-4)

Guidance literature:

In tetrahydrofuran; soln. of Sc-complex in THF was added to stirred soln. of ligand in THF at ambient temp., stirred for 1 h under Ar; filtered, volatiles were removed in vacuo, recrystd. from hexane and toluene at -30°C; elem. anal.;

DOI:10.1021/om020783s

Reference yield: 92.0%

tetrakis(dimethylamido)zirconium (IV) (19756-04-8) + 2,6-bis(2,6-bis((2,6-diisopropylphenyl)amino)methyl)pyridine (184640-73-1) → Zr(N(CH3)2)2(C5H3N(CH2NC6H3(CH(CH3)2)2)2) (184640-76-4)

Guidance literature:

In toluene; N2-atmosphere; refluxing (12 h); evapn. (vac.), extg. (hexanes), filtering, crystn. on concg. (-30°C, 12 h), filtering, drying (vac.); elem. anal.;

DOI:10.1021/om9604278

upstream raw materials:

2,6-diisopropylbenzenamine

2,6-bis[(tosyloxy)methyl]pyridine

Downstream raw materials:

Lu(CH₂SiMe₃)(THF)2(2,6-bis(((2,6-diisopropylphenyl)amino)methyl)pyridine^(2-))

Y(CH₂SiMe₃)(THF)2(2,6-bis(((2,6-diisopropylphenyl)amino)methyl)pyridine^(2-))

Sc(CH₂SiMe₃)(THF)(2,6-bis(((2,6-diisopropylphenyl)amino)methyl)pyridine^(2-))

LuNiPr₂(THF)(2,6-bis(((2,6-diisopropylphenyl)amino)methyl)pyridine^(2-))