((C₆H₅CH₂O)2C₆H₃CH₂O)2C₆H₃CH₂CH(3,5-dimethylpyrazolyl)2

Base Information

• Chemical Name: ((C₆H₅CH₂O)2C₆H₃CH₂O)2C₆H₃CH₂CH(3,5-dimethylpyrazolyl)2
• CAS No.: 918794-25-9
• Molecular Formula: C₆₀H₅₈N₄O₆
• Molecular Weight: 931.144
• Mol file: 918794-25-9.mol

Synonyms:((C₆H₅CH₂O)2C₆H₃CH₂O)2C₆H₃CH₂CH(3,5-dimethylpyrazolyl)2

Chemical Property of ((C₆H₅CH₂O)2C₆H₃CH₂O)2C₆H₃CH₂CH(3,5-dimethylpyrazolyl)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ((C₆H₅CH₂O)2C₆H₃CH₂O)2C₆H₃CH₂CH(3,5-dimethylpyrazolyl)2

There total 1 articles about ((C₆H₅CH₂O)2C₆H₃CH₂O)2C₆H₃CH₂CH(3,5-dimethylpyrazolyl)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

3,5-bis[3,5-bis(benzyloxy)benzyloxy]benzyl bromide (129536-41-0) + 1,1'-methylenebis(3,5-dimethyl-1H-pyrazole) (28791-82-4) → ((C6H5CH2O)2C6H3CH2O)2C6H3CH2CH(3,5-dimethylpyrazolyl)2 (918794-25-9)

Guidance literature:

1,1'-methylenebis(3,5-dimethyl-1H-pyrazole); With n-butyllithium; In tetrahydrofuran; Petroleum ether; at -78 ℃; for 2h;

3,5-bis[3,5-bis(benzyloxy)benzyloxy]benzyl bromide; In tetrahydrofuran; at -78 - 20 ℃;

DOI:10.1039/b607090f

Reference yield: 90.0%

((C6H5CH2O)2C6H3CH2O)2C6H3CH2CH(3,5-dimethylpyrazolyl)2 (918794-25-9) + chloromethyl(1,5-cyclooctadiene)palladium(II) → PdCl(CH3)((CH3)2C3HN2)2CHCH2C6H3(OCH2C6H3(OCH2C6H5)2)2 (1234862-27-1)

Guidance literature:

In diethyl ether; byproducts: C8H12; (Ar), Et2O added to Pd complex and ligand (1:1) at room temp., stirred overnight; evapd.(vac.), washed (pentane), elem. anal.;

DOI:10.1002/ejic.200900869

Reference yield: 87.0%

((C6H5CH2O)2C6H3CH2O)2C6H3CH2CH(3,5-dimethylpyrazolyl)2 (918794-25-9) + dioxomolybdenum(VI) dichloride (13637-68-8) → [MoO2Cl2(((C6H5CH2O)2C6H3CH2O)2C6H3CH2CH(3,5-dimethylpyrazolyl)2)] (1004520-87-9)

Guidance literature:

In tetrahydrofuran; under Ar, Schlenk techniques; bis(pyrazolyl)methane deriv. (1 equiv.) added to soln. of MoCl2O2 in THF, mixt. stirred at room temp. for 1 h; evapn. under vac., residue washed with Et2O and recrystd. from toluene/hexane; elem. anal.;

DOI:10.1039/b710125b

upstream raw materials:

3,5-bis[3,5-bis(benzyloxy)benzyloxy]benzyl bromide

1,1'-methylenebis(3,5-dimethyl-1H-pyrazole)

Downstream raw materials:

[(((C₆H₅CH₂O)2C₆H₃CH₂O)2C₆H₃CH₂CH(C₃H(CH₃)2N₂)2)PdCl₂]

[MoO₂Cl₂(((C₆H₅CH₂O)2C₆H₃CH₂O)2C₆H₃CH₂CH(3,5-dimethylpyrazolyl)2)]

NiBr₂((CH₃)2C₃HN₂)2CHCH₂C₆H₃(OCH₂C₆H₃(OCH₂C₆H₅)2)2

PdCl(CH₃)((CH₃)2C₃HN₂)2CHCH₂C₆H₃(OCH₂C₆H₃(OCH₂C₆H₅)2)2