129536-41-0

Basic information

• Product Name: 3,5-BIS[3,5-BIS(BENZYLOXY)BENZYLOXY]BENZYL BROMIDE
• Synonyms: 3,5-BIS[3,5-BIS(BENZYLOXY)BENZYLOXY]BENZYL BROMIDE;3,5-BIS(3,5-DIBENZYLOXYBENZYLOXY)BENZYL BROMIDE;Bisbisbenzyloxybenzyloxybenzylbromide
• CAS NO: 129536-41-0
• Molecular Formula: C₄₉H₄₃BrO₆
• Molecular Weight: 807.77
• Product Categories: Building Blocks for Dendrimers;Functional Materials
• Mol File: 129536-41-0.mol

Chemical Properties

• Melting Point: 129 °C
• Boiling Point: 894.004°C at 760 mmHg
• Flash Point: 384.274°C
• Appearance: /
• Density: 1.288g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.64
• Storage Temp.: Refrigerator
• CAS DataBase Reference: 3,5-BIS[3,5-BIS(BENZYLOXY)BENZYLOXY]BENZYL BROMIDE(CAS DataBase Reference)
• NIST Chemistry Reference: 3,5-BIS[3,5-BIS(BENZYLOXY)BENZYLOXY]BENZYL BROMIDE(129536-41-0)
• EPA Substance Registry System: 3,5-BIS[3,5-BIS(BENZYLOXY)BENZYLOXY]BENZYL BROMIDE(129536-41-0)

Safety Data

• Hazardous Substances Data: 129536-41-0(Hazardous Substances Data)

Usage

Uses

Used in Catalyst Preparation:
3,5-BIS[3,5-BIS(BENZYLOXY)BENZYLOXY]BENZYL BROMIDE is used as a building block for the preparation of dendronized catalysts. These catalysts are designed to enhance the efficiency and selectivity of various chemical reactions, such as the Henry reaction and the Suzuki-Miyaura reaction. The dendritic structure of the compound allows for the creation of catalysts with multiple active sites, which can improve the overall performance of the catalyst.
Used in Chemical Synthesis:
In the field of chemical synthesis, 3,5-BIS[3,5-BIS(BENZYLOXY)BENZYLOXY]BENZYL BROMIDE is used as a versatile intermediate for the synthesis of various complex organic molecules. Its unique structure and multiple reactive sites make it an attractive candidate for the development of new synthetic routes and the construction of novel molecular architectures.
Used in Materials Science:
3,5-BIS[3,5-BIS(BENZYLOXY)BENZYLOXY]BENZYL BROMIDE is also used in materials science for the development of advanced materials with tailored properties. The compound's dendritic structure can be exploited to create materials with enhanced mechanical, thermal, or electrical properties, depending on the specific application requirements.
Used in Drug Delivery Systems:
In the pharmaceutical industry, 3,5-BIS[3,5-BIS(BENZYLOXY)BENZYLOXY]BENZYL BROMIDE can be used as a component in the design of drug delivery systems. The compound's structural properties allow for the development of dendrimers with multiple functional groups, which can be used to attach drug molecules and target specific biological receptors. This can lead to improved drug delivery, enhanced bioavailability, and reduced side effects.
Used in Analytical Chemistry:
3,5-BIS[3,5-BIS(BENZYLOXY)BENZYLOXY]BENZYL BROMIDE can also find applications in analytical chemistry as a reagent or a component in the development of novel analytical methods. The compound's unique structure and multiple reactive sites can be exploited to create new detection schemes or to improve the sensitivity and selectivity of existing analytical techniques.

InChI:InChI=1/C49H43BrO6/c50-30-41-21-44(55-35-42-23-46(51-31-37-13-5-1-6-14-37)28-47(24-42)52-32-38-15-7-2-8-16-38)27-45(22-41)56-36-43-25-48(53-33-39-17-9-3-10-18-39)29-49(26-43)54-34-40-19-11-4-12-20-40/h1-29H,30-36H2

Upstream product

• 2150-44-9 1-carbomethoxy-3,5-dihydroxybenzene 
• 137472-14-1 methyl 3,5-bis[[3,5-bis(phenylmethoxy)phenyl]methoxy] benzoate 
• 100-39-0 benzyl bromide 
• 137472-18-5 3,5-bis(3,5-bis(benzyloxy)benzyloxy)benzaldehyde 
• 80457-61-0 methanesulfonyl 3,5-dibenzyloxybenzyl alcohol 
• 29654-55-5 5-(hydroxymethyl)benzene-1,3-diol 
• 24131-32-6 3,5-bis(benzyloxy)benzyl bromide 
• 24131-31-5 3,5-dibenzyloxybenzyl alcohol 
• 99-10-5 3,5-Dihydroxybenzoic acid 
• 58605-10-0 methyl 3,5-bis(benzyloxy)benzoate 
• 246512-25-4 methanesulfonic acid 3,5-bis-(3,5-bis-benzyloxy-benzyloxy)-benzyl ester 
• 129536-40-9 [3,5-Bis-(3,5-bis-benzyloxy-benzyloxy)-phenyl]-methanol 

Downstream Products

• 137472-16-3 [3,5-bis[[3,5-bis[[3,5-bis(phenylmethoxy)phenyl]methoxy]phenyl]methoxy]phenyl]methyl alcohol 
• 278610-81-4 3-[3,5-Bis-(3,5-bis-benzyloxy-benzyloxy)-benzyloxy]-5-hydroxymethyl-phenol 
• 143345-09-9 C₁₀₇H₉₁Cl₃O₁₆ 
• 143330-95-4 3-[3,5-Bis-(3,5-bis-benzyloxy-benzyloxy)-benzyloxy]-5-hydroxy-benzoic acid 2,2,2-trichloro-ethyl ester 
• 156666-25-0 rac-2-<(Benzyloxy)methyl>-3-<<3,5-bis(benzyloxy)benzyl>oxy>-1-<<3,5-bis<<3,5-bis(benzyloxy)benzyl>oxy>benzyl>oxy>-2-<<(2-methoxyethoxy)methoxy>methyl>propane 

Relevant articles and documents

Preparation of polymers with controlled molecular architecture. A new convergent approach to dendritic macromolecules

The novel convergent growth approach to topological macromolecules based on dendritic fragments is described. The polyether dendritic fragments are prepared by starting from what will become the periphery of the molecule and progressing inward. In the fir

A New Convergent Approach to Monodisperse Dendritic Macromolecules

A novel convergent approach for the synthesis of dendritic macromolecules is presented and its scope and versatility demonstrated with the synthesis of a series of monodisperse dendritic polyether macromolecules based on 3,5-dihydroxybenzyl alcohol as the

Dendrimer solid acid and polymer electrolyte membrane including the same

Provided are a dendrimer solid acid and a polymer electrolyte membrane using the same. The polymer electrolyte membrane includes a macromolecule of a dendrimer solid acid having ionically conductive terminal groups at the surface thereof and a minimum amo

Stabilization of G-quadruplex DNA with platinum(II) Schiff base complexes: Luminescent probe and down-regulation of c-myc oncogene expression

The interactions of a series of platinum(II) Schiff base complexes with c-myc G-quadruplex DNA were studied. Complex [PtL1a] (1a; H 2L1a= N,N'-bis(salicylidene)-4,5-methoxy-1,2- phenylenediamine) can moderately inhibit c-m

Synthesis of organometallic poly(dendrimer)s by macromonomer polymerization: effect of dendrimer size and structural rigidity on the polymerization efficiency

Two series of first to third generation (G1-G3) oligoether dendrimers, one hearing a shorter spacer chain (C-O) and the other having a longer spacer branch (C-C-C-O) were prepared. Both series of compounds, containing two reactive C≡CH moieties on the dendrimer surface, were used as macromonomers and copolymerized with trans-[Pt(PEt3)2Cl2] to form organometallic poly(dendrimer)s by an outer-sphere-outer-sphere connection strategy. It was found that concentration of monomer used in the polymerization, the dendrimer generation, and, most strikingly, the length of the spacer were key factors that determined the polymerization efficiency. Hence, the structurally more rigid and compact C-O linked dendrimers formed poly(dendrimer)s with a higher degree of polymerization than the structurally less rigid and more bulky C-C-C-O dendrimers. This result was due to the higher tendency to form cyclic oligomers in the latter series of compounds. In addition, the differences in the polymerization efficiency among the three generations of dendrimers could be explained by the gradual decrease of reactive functional group density on the dendrimer surface.

Triazole-linked dendro[60]fullerenes: modular synthesis via a 'click' reaction and acidity-dependent self-assembly on the surface

A series of Fréchet-type dendron functionalized [60]fullerene derivatives that bear a 1,2,3-triazole linkage group, referred to as triazole-linked dendro[60]fullerenes, were prepared via a modular synthetic protocol based on a Cu-catalyzed [3+2] cycloaddi

Dendritic chiral phosphine lewis bases-catalyzed asymmetric aza-Morita-Baylis-Hillman reaction of N-sulfonated imines with activated olefins

A series of polyether dendritic chiral phosphine Lewis bases was synthesized, and successfully applied to the asymmetric aza-Morita - Baylis - Hill -man reaction of N - sulfonated imines (N - arylmethyl -idene-4- methylbenzenesulfonamides) with methyl vin

Synthesis of dendritic phenol ether derivatives with a naphthalene core

A series of dendritic phenol ether derivatives with a naphthalene core were synthesized by the Williamson reaction as a coupling reaction between 1-hydroxymethylnaphthalene and polyether-based dendritic fragments in the presence of phase-transfer catalyst and alkali. The modified method for chlorination of dendritic benzyl alcohol was also developed using PPh3 and CCl4 as reagents and CH2Cl2/CCl4 as solvent. Copyright Taylor & Francis Group, LLC.

Hydrogen-bonded dendronized polymers and their self-assembly in solution

Frechet-type benzyl ether dendrons of second and third generations with a carboxyl group (G2, G3) at the apex site could attach to poly(4-vinylpyridine) (PVP), forming hydrogen-bonded dendronized polymers (HB denpols) in their common solvent, chloroform. The HB denpols show unique self-assembly behavior, forming vesicles in the common solvent under ultrasonic treatment. The structure and morphology of the vesicles were characterized by dynamic light scattering (DLS), static light scattering (SLS), SEM, TEM, and AFM. The size of the vesicles decreases and the thickness of the vascular membrane increases as the molar ratio of Gx/PVP increases. The hydrogen bonding. π-π aromatic stacking of the dendrons. and the considerable difference in architecture between the dendron Gx and PVP are the main factors facilitating the assembly of the HB denpols in the common solvent.

Optical switching and antenna effect of dendrimers with an anthracene core

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