(2E,4E)-5-(benzyldimethylsilyl)-4,5-dideutero-3-methylpenta-2,4-dien-1-ol

Base Information

Chemical Name:(2E,4E)-5-(benzyldimethylsilyl)-4,5-dideutero-3-methylpenta-2,4-dien-1-ol
CAS No.:1430344-90-3
Molecular Formula:C₁₅H₂₂OSi
Molecular Weight:248.409
Hs Code.:

Synonyms:(2E,4E)-5-(benzyldimethylsilyl)-4,5-dideutero-3-methylpenta-2,4-dien-1-ol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2E,4E)-5-(benzyldimethylsilyl)-4,5-dideutero-3-methylpenta-2,4-dien-1-ol

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Technology Process of (2E,4E)-5-(benzyldimethylsilyl)-4,5-dideutero-3-methylpenta-2,4-dien-1-ol

There total 2 articles about (2E,4E)-5-(benzyldimethylsilyl)-4,5-dideutero-3-methylpenta-2,4-dien-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1631-70-5
benzyldimethylsilane

: 1430344-90-3
(2E,4E)-5-(benzyldimethylsilyl)-4,5-dideutero-3-methylpenta-2,4-dien-1-ol

Guidance literature:: Multi-step reaction with 2 steps

1.1: lithium aluminium deuteride / diethyl ether / 0.5 h / 0 °C / Inert atmosphere

2.1: platinum⁽⁰⁾-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex; tri-tert-butyl phosphine / tetrahydrofuran; 5,5-dimethyl-1,3-cyclohexadiene / 0.5 h / Inert atmosphere

2.2: Inert atmosphere

With lithium aluminium deuteride; platinum⁽⁰⁾-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex; tri-tert-butyl phosphine; In tetrahydrofuran; 5,5-dimethyl-1,3-cyclohexadiene; diethyl ether;
DOI:10.1002/chem.201202260

Reference yield:

: 1430344-94-7
(E)-2-[(5-deutero-3-methylpent-2-en-4-yn-1-yl)oxy]tetrahydro-2H-pyran

: 1430344-90-3
(2E,4E)-5-(benzyldimethylsilyl)-4,5-dideutero-3-methylpenta-2,4-dien-1-ol

Guidance literature:: Multi-step reaction with 2 steps

1.1: toluene-4-sulfonic acid / methanol / 0.25 h / Inert atmosphere

2.1: platinum⁽⁰⁾-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex; tri-tert-butyl phosphine / tetrahydrofuran; 5,5-dimethyl-1,3-cyclohexadiene / 0.5 h / Inert atmosphere

2.2: Inert atmosphere

With platinum⁽⁰⁾-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex; tri-tert-butyl phosphine; toluene-4-sulfonic acid; In tetrahydrofuran; methanol; 5,5-dimethyl-1,3-cyclohexadiene;
DOI:10.1002/chem.201202260

Reference yield: 78.0%

: 1430344-90-3
(2E,4E)-5-(benzyldimethylsilyl)-4,5-dideutero-3-methylpenta-2,4-dien-1-ol

: 138846-06-7
2-[(1’E,3’E)-3’-methyl-4’-iodobuta-1’,3’-dien-1’yl]-1,3,3-trimethylcyclohex-1-ene

: 58508-29-5
trans-11,12-dideuteroretinol

Guidance literature:: (2E,4E)-5-(benzyldimethylsilyl)-4,5-dideutero-3-methylpenta-2,4-dien-1-ol; With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 20 ℃; for 0.5h; Inert atmosphere; Darkness;

2-[(1’E,3’E)-3’-methyl-4’-iodobuta-1’,3’-dien-1’yl]-1,3,3-trimethylcyclohex-1-ene; With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; In tetrahydrofuran; for 1h; Inert atmosphere; Darkness;
DOI:10.1002/chem.201202260