2,5-Furandicarboxaldehyde, radical ion(1-) (9CI)

Base Information

• Chemical Name: 2,5-Furandicarboxaldehyde, radical ion(1-) (9CI)
• CAS No.: 163857-09-8
• Molecular Formula: C₆H₄O₃
• Molecular Weight: 124.096
• Mol file: 163857-09-8.mol

Synonyms:2,5-Furandicarboxaldehyde, radical ion(1-) (9CI)

Chemical Property of 2,5-Furandicarboxaldehyde, radical ion(1-) (9CI)

Chemical Property:

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,5-Furandicarboxaldehyde, radical ion(1-) (9CI)

There total 131 articles about 2,5-Furandicarboxaldehyde, radical ion(1-) (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

5-hydroxymethyl-2-furfuraldehyde (67-47-0) → 2,5-diformylfurane (823-82-5,163857-09-8) + 5-Formyl-2-furancarboxylic acid (13529-17-4)

Guidance literature:

With oxygen; In dimethyl sulfoxide; at 140 ℃; for 24h; Reagent/catalyst; Temperature;

DOI:10.1039/c5gc02794b

Reference yield: 82.0%

5-hydroxymethyl-2-furfuraldehyde (67-47-0) → 2,5-diformylfurane (823-82-5,163857-09-8) + 5-Formyl-2-furancarboxylic acid (13529-17-4) + furan-2,5-dicarboxylic acid (3238-40-2)

Guidance literature:

With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; laccase from panus conchatus; oxygen; In aq. acetate buffer; at 25 ℃; for 96h; pH=4.5; Reagent/catalyst; Enzymatic reaction;

DOI:10.1039/c5gc00788g

Reference yield: 62.0%

5-(iodomethyl)furan-2-carbaldehyde (76154-40-0) → 2,5-diformylfurane (823-82-5,163857-09-8) + 5-Formyl-2-furancarboxylic acid (13529-17-4)

Guidance literature:

With dimethyl sulfoxide; at 150 ℃; for 18h;

DOI:10.1002/cctc.201400023

upstream raw materials:

furan

N,N-dimethyl-formamide

5-hydroxymethyl-2-furfuraldehyde

2,5-bis-(hydroxymethyl)furan

Downstream raw materials:

2,5-bis[hydroxy(phenyl)methyl]furan

3-[5-(3-hydroxy-propyl)-furan-2-yl]-propan-1-ol

5-Formyl-2-furancarboxylic acid

furan-2,5-dicarboxylic acid

Refernces

• 1、 Cho, Ahra,Byun, Sangmoon,Cho, Jin Hee,Kim, Byeong Moon. "AuPd-Fe3O4 Nanoparticle-Catalyzed Synthesis of Furan-2,5-dimethylcarboxylate from 5-Hydroxymethylfurfural under Mild Conditions". . p. 2310 - 2317. Retrieved 2019.
• 2、 Mittal, Neha,Nisola, Grace M.,Seo, Jeong Gil,Lee, Seong-Poong,Chung, Wook-Jin. "Organic radical functionalized SBA-15 as a heterogeneous catalyst for facile oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran". . p. 106 - 114. Retrieved 2015.
• 3、 Pal, Priyanka,Saravanamurugan, Shunmugavel. "Heterostructured manganese catalysts for the selective oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran". . . Retrieved 2020.
• 4、 Xu, Fenghua,Zhang, Zehui. "Polyaniline-grafted VO(acac)2: An effective catalyst for the synthesis of 2,5-diformylfuran from 5-hydroxymethylfurfural and fructose". . p. 1470 - 1477. Retrieved 2015.
• 5、 Xiang, Xi,He, Ling,Yang, Yu,Guo, Bin,Tong, Dongmei,Hu, Changwei. "A one-pot two-step approach for the catalytic conversion of glucose into 2,5-diformylfuran". . p. 735 - 741. Retrieved 2011.
• 6、 Liu, Bing,Ren, Yongshen,Zhang, Zehui. "Aerobic oxidation of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid in water under mild conditions". . p. 1610 - 1617. Retrieved 2015.
• 7、 Yuan, Ziliang,Liu, Bing,Zhou, Peng,Zhang, Zehui,Chi, Quan. "Aerobic oxidation of biomass-derived 5-hydroxymethylfurfural to 2,5-diformylfuran with cesium-doped manganese dioxide". . p. 4430 - 4439. Retrieved 2018.
• 8、 Li, Gang,Sun, Zhen,Yan, Yueer,Zhang, Yahong,Tang, Yi. "Direct Transformation of HMF into 2,5-Diformylfuran and 2,5-Dihydroxymethylfuran without an External Oxidant or Reductant". . p. 494 - 498. Retrieved 2017.
• 9、 Ayoub, Nadim,Bergère, Carla,Toufaily, Joumana,Guénin, Erwann,Enderlin, Gérald. "A gram scale selective oxidation of 5-hydroxymethylfurfural to diformylfuran in the presence of oxone and catalyzed by 2-iodobenzenesulfonic acid". . p. 11577 - 11583. Retrieved 2020.
• 10、 Smirnova,Klushin,Bezbozhnaya,Khomutova,Lobachev,Mitchenko. "Selective Oxidation of 5-(Hydroxymethyl)furfural to Furan-2,5-dicarbaldehyde with Sodium Nitrite in Phosphoric Acid". . p. 414 - 418. Retrieved 2018.