1-(2-(benzyloxymethyl)allyl)-N,N-diethyl-1,1-dimethylsilanamine

Base Information

• Chemical Name: 1-(2-(benzyloxymethyl)allyl)-N,N-diethyl-1,1-dimethylsilanamine
• CAS No.: 1197189-71-1
• Molecular Formula: C₁₇H₂₉NOSi
• Molecular Weight: 291.509
• Mol file: 1197189-71-1.mol

Synonyms:1-(2-(benzyloxymethyl)allyl)-N,N-diethyl-1,1-dimethylsilanamine

Chemical Property of 1-(2-(benzyloxymethyl)allyl)-N,N-diethyl-1,1-dimethylsilanamine

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 1-(2-(benzyloxymethyl)allyl)-N,N-diethyl-1,1-dimethylsilanamine

There total 1 articles about 1-(2-(benzyloxymethyl)allyl)-N,N-diethyl-1,1-dimethylsilanamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 23.0%

(N,N-diethylamino)dimethylchlorosilane (6026-02-4) + 1-{[2-((chloromethyl)allyl)oxy]methyl}-4-methoxybenzene (113964-32-2) → 1-(2-(benzyloxymethyl)allyl)-N,N-diethyl-1,1-dimethylsilanamine (1197189-71-1)

Guidance literature:

1-{[2-((chloromethyl)allyl)oxy]methyl}-4-methoxybenzene; With magnesium; ethylene dibromide; In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere;

(N,N-diethylamino)dimethylchlorosilane; In tetrahydrofuran; at -78 - 20 ℃; Inert atmosphere;

DOI:10.1021/ol902400q

Reference yield: 99.0%

1-(2-(benzyloxymethyl)allyl)-N,N-diethyl-1,1-dimethylsilanamine (1197189-71-1) + lithium enolate of 1-tetralone (74074-96-7) → (2-(benzyloxymethyl)allyl)(3,4-dihydronaphthalen-1-yloxy)dimethylsilane (1197189-45-9)

Guidance literature:

1-(2-(benzyloxymethyl)allyl)-N,N-diethyl-1,1-dimethylsilanamine; With acetyl chloride; In tetrahydrofuran; at 0 ℃; Inert atmosphere;

lithium enolate of 1-tetralone; In tetrahydrofuran; at -78 - 20 ℃; Inert atmosphere;

DOI:10.1021/ol902400q

Reference yield: 99.0%

1-(2-(benzyloxymethyl)allyl)-N,N-diethyl-1,1-dimethylsilanamine (1197189-71-1) + Lithium; (R)-3-isopropenyl-6-methyl-cyclohexa-1,5-dienolate → (R)-(2-(benzyloxymethyl)allyl)dimethyl(6-methyl-3-(prop-1-en-2-yl)cyclohexa-1,5-dienyloxy)silane (1197189-50-6)

Guidance literature:

1-(2-(benzyloxymethyl)allyl)-N,N-diethyl-1,1-dimethylsilanamine; With acetyl chloride; In tetrahydrofuran; at 0 ℃; Inert atmosphere;

Lithium; (R)-3-isopropenyl-6-methyl-cyclohexa-1,5-dienolate; In tetrahydrofuran; at -78 - 20 ℃; Inert atmosphere;

DOI:10.1021/ol902400q

upstream raw materials:

(N,N-diethylamino)dimethylchlorosilane

1-{[2-((chloromethyl)allyl)oxy]methyl}-4-methoxybenzene

Downstream raw materials:

(2-(benzyloxymethyl)allyl)(4,4-dimethylcyclohexa-1,5-dienyloxy)dimethylsilane

(2-(benzyloxymethyl)allyl)(3,4-dihydronaphthalen-1-yloxy)dimethylsilane

(Z)-(2-(benzyloxymethyl)allyl)dimethyl(1-phenylprop-1-enyloxy)silane

(R)-(2-(benzyloxymethyl)allyl)dimethyl(6-methyl-3-(prop-1-en-2-yl)cyclohexa-1,5-dienyloxy)silane