Chloro(diethylamino)dimethylsilane

Base Information

• Chemical Name: Chloro(diethylamino)dimethylsilane
• CAS No.: 6026-02-4
• Molecular Formula: C6H16ClNSi
• Molecular Weight: 165.738
• Hs Code.: 2931900090
• European Community (EC) Number: 624-221-2
• DSSTox Substance ID: DTXSID40454947
• Nikkaji Number: J1.464.247A
• Mol file: 6026-02-4.mol

Synonyms:Chloro(diethylamino)dimethylsilane;6026-02-4;N-[chloro(dimethyl)silyl]-N-ethylethanamine;CHLORO(DIETHYLAMINO)DIMETHYLSILANE 97;SCHEMBL2102625;(Diethylamino)dimethylchlorosilane;DTXSID40454947;AKOS015894748;(CHLORODIMETHYLSILYL)DIETHYLAMINE

Chemical Property of Chloro(diethylamino)dimethylsilane

Chemical Property:

• Refractive Index: n20/D 1.4300
• Flash Point: 79 °F
• PSA: 3.24000
• Density: 0.829 g/mL at 25 °C
• LogP: 2.26880
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 165.0740537
• Heavy Atom Count: 9
• Complexity: 81.1

Purity/Quality:

99% ^*data from raw suppliers

CHLORO (DIETHYLAMINO) DIMETHYL SILANE 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C
• Statements: 10-14-34
• Safety Statements: 16-26-36/37/39-43-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCN(CC)[Si](C)(C)Cl

Technology Process of Chloro(diethylamino)dimethylsilane

There total 6 articles about Chloro(diethylamino)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

diethylamine (109-89-7) + dimethylsilicon dichloride (75-78-5,30107-43-8) → (N,N-diethylamino)dimethylchlorosilane (6026-02-4)

Guidance literature:

In diethyl ether; at 0 ℃; for 5h; Inert atmosphere; Schlenk technique;

DOI:10.1002/anie.201400405

Reference yield: 80.0%

bis(diethylamino)dimethylsilane (4669-59-4) → (N,N-diethylamino)dimethylchlorosilane (6026-02-4)

Guidance literature:

With dimethylsilicon dichloride; at 20 ℃; for 6h;

DOI:10.1139/v00-025

Reference yield: 65.9%

bis(diethylamino)dimethylsilane (4669-59-4) + Gallium trichloride (13450-90-3) → Cl2Ga(N(CH2CH3)2)2Si(CH3)2(1+)*(Cl3Ga)2N(CH2CH3)2(1-)={Cl2Ga(N(CH2CH3)2)2Si(CH3)2}{(Cl3Ga)2N(CH2CH3)2} (136546-95-7) + (N,N-diethylamino)dimethylchlorosilane (6026-02-4)

Guidance literature:

In diethyl ether; GaCl3 was dissolved in diethyl ether, stirred soln. was cooled in an ice bath, addn. of the silane, the soln. was refluxed for 7 h, pptn., all steps under N2 or Ar; the liquid portion was removed from the solid by vacuum distn., the solid was recrystd. (CH2Cl2), elem. anal.;

upstream raw materials:

diethylamine

dimethylsilicon dichloride

bis(diethylamino)dimethylsilane

lithium diethylamide

Downstream raw materials:

Diaethylamino-dimethyl--silan

Bis--methyl-phosphin

N-(Diethylamino-dimethyl-silyl)-benzophenon-imin

bis(2,2-dimethylhydrazino)dimethylsilane