tetrabutylammonium pentacarbonylmanganate(I)

Base Information

• Chemical Name: tetrabutylammonium pentacarbonylmanganate(I)
• CAS No.: 68433-36-3
• Molecular Formula: C₅MnO₅*C₁₆H₃₆N
• Molecular Weight: 437.459
• Mol file: 68433-36-3.mol

Synonyms:tetrabutylammonium pentacarbonylmanganate(I)

Chemical Property of tetrabutylammonium pentacarbonylmanganate(I)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of tetrabutylammonium pentacarbonylmanganate(I)

There total 1 articles about tetrabutylammonium pentacarbonylmanganate(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(CO)5MnCH(C6H5)OSi(CH3)3 (68433-34-1) + tetra-n-butylammoniumfluoride trihydrate (22206-57-1,153005-55-1) → (C4H9)4N(1+)*Mn(CO)5(1-)=[(C4H9)4N][Mn(CO)5] (68433-36-3) + (CO)5MnCH(C6H5)OH + benzaldehyde (100-52-7)

Guidance literature:

In tetrahydrofuran; 25°C; not sepd., detected by IR;

DOI:10.1021/ja00267a015

Reference yield:

tetrabutylammonium pentacarbonylmanganate(I) (68433-36-3) → dimanganese decacarbonyl (10170-69-1)

Guidance literature:

With V(CO)6; In toluene; byproducts: V(CO)6(1-); N2 or Ar, Mn-complex partially dissolved and treated with V(CO)6 at about -50°C, temp. raised to room temp.; mechanism discussed (reaction with (13)CO); detn. by IR;

Reference yield:

3,5-Di-tert-butylcatechol (1020-31-1,122983-47-5,881376-69-8) + (C4H9)4N(1+)*Mn(CO)5(1-)=[(C4H9)4N][Mn(CO)5] (68433-36-3) → (C4H9)4N(1+)*{Mn(CO)3(C6H2O2(C(CH3)3)2)}(1-)*0.17C6H6={(C4H9)4N}{Mn(CO)3(C6H2O2(C(CH3)3)2)}*0.17C6H6

Guidance literature:

In dichloromethane; byproducts: CO; soln. of ligand added dropwise to soln. of complex, color changed, stirred for 15 min, addn. of benzene; distilled under vac., volume reduced, filtered, washed (cold, deoxygenated benzene);

upstream raw materials:

(CO)5MnCH(C₆H₅)OSi(CH₃)3

tetra-n-butylammoniumfluoride trihydrate

Downstream raw materials:

dimanganese decacarbonyl