4-chlorophenyl diethoxyphosphanecarboxylate oxide

Base Information

• Chemical Name: 4-chlorophenyl diethoxyphosphanecarboxylate oxide
• CAS No.: 72305-96-5
• Molecular Formula: C11H14 Cl O5 P
• Molecular Weight: 292.6526
• Mol file: 72305-96-5.mol

Synonyms:Phosphinecarboxylicacid, diethoxy-, 4-chlorophenyl ester, oxide (9CI)

Chemical Property of 4-chlorophenyl diethoxyphosphanecarboxylate oxide

Chemical Property:

• Vapor Pressure: 5.04E-05mmHg at 25°C
• Boiling Point: 348.4°Cat760mmHg
• Flash Point: 236.7°C
• PSA: 71.64000
• Density: 1.298g/cm³
• LogP: 4.10490

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-chlorophenyl diethoxyphosphanecarboxylate oxide

There total 2 articles about 4-chlorophenyl diethoxyphosphanecarboxylate oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

4-Chlorophenyl chloroformate (7693-45-0) + triethyl phosphite (122-52-1) → diethyl 4-chlorophenoxycarbonylphosphonate (72305-96-5)

Guidance literature:

DOI:10.1021/jm00356a028

Reference yield:

4-Chlorophenyl chloroformate (7693-45-0) → diethyl 4-chlorophenoxycarbonylphosphonate (72305-96-5)

Guidance literature:

With triethyl phosphite;

Reference yield: 97.0%

diethyl 4-chlorophenoxycarbonylphosphonate (72305-96-5) → C9H9ClO5P(1-)*Na(1+) (83877-30-9)

Guidance literature:

With sodium iodide; In tetrahydrofuran; for 120h;

DOI:10.1021/jm00356a028

upstream raw materials:

4-Chlorophenyl chloroformate

triethyl phosphite

Downstream raw materials:

Disodium p-chlorophenoxycarbonylphosphonate

C₉H₉ClO₅P^(1-)*Na⁽¹⁺⁾

Refernces

• 1、 -. "PHOSPHONOFORMIC ACID ESTERS". . . Retrieved 2008/06/13.