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4-chlorophenyl chloroformate
Cas No: 7693-45-0
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
High quality 4-Chlorophenyl Chloroformate supplier in China
Cas No: 7693-45-0
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4-Chlorophenyl ChloroforMate
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No Data 1 Kilogram 20 Metric Ton/Month Henan Allgreen Chemical Co.,Ltd Contact Supplier
4-Chlorophenyl carbonochloridate
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No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier
Pharmaceutical Grade CAS 7693-45-0 with competitive price
Cas No: 7693-45-0
USD $ 139.0-210.0 / Kilogram 1 Kilogram 1000 Kilogram/Day Zhuozhou Wenxi import and Export Co., Ltd Contact Supplier
CAS NO.:7693-45-0
Cas No: 7693-45-0
No Data No Data 10000 Metric Ton/Month Henan Wentao Chemical Product Co., Ltd. Contact Supplier
Carbonochloridic acid,4-chlorophenyl ester 7693-45-0
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4-Chlorophenylchloroformate
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4-Chlorophenyl Chloroformate
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No Data No Data No Data Xiamen Hisunny Chemical Co.,Ltd Contact Supplier
Factory Supply 4-chlorophenyl chloroformate
Cas No: 7693-45-0
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7693-45-0 Usage

Uses

It is widely used as an chemical intermediate and in research purpose. 4-Chlorophenyl chloroformate was used in the preparation of N-hydroxy-N-methylcarbamate 4-chlorophenyl ester.

Uses

4-Chlorophenyl chloroformate was used in the preparation of N-hydroxy-N-methylcarbamate 4-chlorophenyl ester.
InChI:InChI=1/C7H4Cl2O2/c8-5-1-3-6(4-2-5)11-7(9)10/h1-4H

7693-45-0 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Alfa Aesar (31175)  4-Chlorophenyl chloroformate    7693-45-0 10g 911.0CNY Detail
Alfa Aesar (31175)  4-Chlorophenyl chloroformate    7693-45-0 50g 3632.0CNY Detail
Aldrich (363871)  4-Chlorophenylchloroformate  98% 7693-45-0 363871-5G 711.36CNY Detail

7693-45-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 4-Chlorophenyl Chloroformate

1.2 Other means of identification

Product number -
Other names (4-chlorophenyl) carbonochloridate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:7693-45-0 SDS

7693-45-0Synthetic route

4-chloro-phenol
106-48-9

4-chloro-phenol

triphenylphosphine
603-35-0

triphenylphosphine

4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

Conditions
ConditionsYield
With CoCl2 In phosgene85%
4-chlorophenyl chlorothionoformate
937-64-4

4-chlorophenyl chlorothionoformate

A

4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

B

perfluoro(2,4-dimethyl-3-oxa-2,4-diazapentane)
6141-72-6

perfluoro(2,4-dimethyl-3-oxa-2,4-diazapentane)

C

C9H4ClF6NO3

C9H4ClF6NO3

D

C9H4ClF6NO2S

C9H4ClF6NO2S

Conditions
ConditionsYield
In trichlorofluoromethane for 48h; Ambient temperature;A 23%
B 12%
C 12%
D 65%
phosgene
75-44-5

phosgene

sodium 4-chlorophenolate
1193-00-6

sodium 4-chlorophenolate

4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

Conditions
ConditionsYield
In toluene; benzene for 2h; Ambient temperature;60%
phosgene
75-44-5

phosgene

antipyrine
60-80-0

antipyrine

4-chloro-phenol
106-48-9

4-chloro-phenol

4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

phosgene
75-44-5

phosgene

4-chloro-phenol
106-48-9

4-chloro-phenol

4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

Conditions
ConditionsYield
With antipyrine
With pyridine In dichloromethane at 0℃;
bis(trichloromethyl) carbonate
32315-10-9

bis(trichloromethyl) carbonate

4-chloro-phenol
106-48-9

4-chloro-phenol

4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran at 0 - 40℃; for 0.5h;
With triethylamine In tetrahydrofuran at 0 - 20℃; for 6.25h; Inert atmosphere;
With N,N-diethylaniline In toluene at 20℃; for 2h; Cooling with ice;
With triethylamine In dichloromethane at 0℃; for 0.5h;
4-chloro-phenol
106-48-9

4-chloro-phenol

4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 77 percent / NaH / benzene; diethyl ether / 0.5 h
2: 60 percent / benzene; toluene / 2 h / Ambient temperature
View Scheme
4-chloro-phenol
106-48-9

4-chloro-phenol

trichloromethyl chloroformate
503-38-8

trichloromethyl chloroformate

4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

Conditions
ConditionsYield
With dmap In toluene at 20℃; for 24h;
(2-fluoro-4-methoxyphenyl)hydrazine

(2-fluoro-4-methoxyphenyl)hydrazine

4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

4-chlorophenyl 2-(2-fluoro-4-methoxyphenyl)hydrazinecarboxylate
1169939-59-6

4-chlorophenyl 2-(2-fluoro-4-methoxyphenyl)hydrazinecarboxylate

Conditions
ConditionsYield
With pyridine In 1-methyl-pyrrolidin-2-one at 0 - 20℃; for 1.5h;100%
4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

3'-azido-2',3'-deoxythymidine
30516-87-1

3'-azido-2',3'-deoxythymidine

C17H16ClN5O6
1355331-53-1

C17H16ClN5O6

Conditions
ConditionsYield
With pyridine100%
4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

C2HF3O2*C13H23NO3S
400899-68-5

C2HF3O2*C13H23NO3S

C20H26ClNO5S
400899-69-6

C20H26ClNO5S

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine In dichloromethane at 0℃; for 0.75h; Inert atmosphere;100%
4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

3, 5-dinitroaniline
618-87-1

3, 5-dinitroaniline

4-chlorophenyl 3,5-dinitrophenylcarbamate

4-chlorophenyl 3,5-dinitrophenylcarbamate

Conditions
ConditionsYield
In tetrahydrofuran at 20℃;99%
4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

N-Phenylhydroxylamine
100-65-2

N-Phenylhydroxylamine

N-hydroxy-N-phenylcarbamate 4-chlorophenyl ester
4645-77-6

N-hydroxy-N-phenylcarbamate 4-chlorophenyl ester

Conditions
ConditionsYield
With potassium carbonate In diethyl ether; water at 4℃;98%
With potassium carbonate In diethyl ether; water at 0 - 20℃; for 1.5h;91%
trans-4-methylaminomethyl-cyclohexanecarboxylic acid hydrochloride

trans-4-methylaminomethyl-cyclohexanecarboxylic acid hydrochloride

4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

trans-4-{[(4-chloro-phenoxy-carbonyl)-methyl-amino]-methyl}-cyclohexanecarboxylic acid

trans-4-{[(4-chloro-phenoxy-carbonyl)-methyl-amino]-methyl}-cyclohexanecarboxylic acid

Conditions
ConditionsYield
Stage #1: trans-4-methylaminomethyl-cyclohexanecarboxylic acid hydrochloride With 1,1,1,3,3,3-hexamethyl-disilazane at 140℃; for 2.5h; Heating / reflux;
Stage #2: 4-Chlorophenyl chloroformate In tetrahydrofuran at 0 - 20℃;
98%
Stage #1: trans-4-methylaminomethyl-cyclohexanecarboxylic acid hydrochloride With 1,1,1,3,3,3-hexamethyl-disilazane at 140℃; for 2.5h;
Stage #2: 4-Chlorophenyl chloroformate In tetrahydrofuran at 0 - 20℃;
98%
4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

C30H33N9O6

C30H33N9O6

C72H51Cl6N9O18

C72H51Cl6N9O18

Conditions
ConditionsYield
In tetrahydrofuran at 20℃;97.8%
4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

C78H81N21O18

C78H81N21O18

C162H117Cl12N21O42

C162H117Cl12N21O42

Conditions
ConditionsYield
In tetrahydrofuran at 20℃;97.8%
4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

Methyl 3,4-di-O-benzyl-2-O-para-chlorophenylcarbonyl-6-O-triisopropylsilyl-β-D-glucopyranoside
331281-71-1

Methyl 3,4-di-O-benzyl-2-O-para-chlorophenylcarbonyl-6-O-triisopropylsilyl-β-D-glucopyranoside

Methyl 3,4-di-O-benzyl-2-O-para-chlorophenylcarbonyl-6-O-triisopropylsilyl-β-D-glucopyranoside
331281-69-7

Methyl 3,4-di-O-benzyl-2-O-para-chlorophenylcarbonyl-6-O-triisopropylsilyl-β-D-glucopyranoside

Conditions
ConditionsYield
With pyridine; dmap In dichloromethane at 20℃; for 1h;96%
4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

N-methylhydroxyamine hydrochloride
4229-44-1

N-methylhydroxyamine hydrochloride

N-hydroxy-N-methylcarbamate 4-chlorophenyl ester
13649-16-6

N-hydroxy-N-methylcarbamate 4-chlorophenyl ester

Conditions
ConditionsYield
With potassium carbonate In diethyl ether; water96%
With potassium carbonate In diethyl ether at 20℃; for 5h;55%
4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

N-methylhydroxyamine hydrochloride
4229-44-1

N-methylhydroxyamine hydrochloride

potassium carbonate
584-08-7

potassium carbonate

A

4-chlorophenyl ester

4-chlorophenyl ester

B

N-hydroxy-N-methylcarbamate 4-chlorophenyl ester
13649-16-6

N-hydroxy-N-methylcarbamate 4-chlorophenyl ester

Conditions
ConditionsYield
In hexane; Dimethyl ether; waterA 96%
B n/a
4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

C32H50O9
1571914-67-4

C32H50O9

C39H53ClO11

C39H53ClO11

Conditions
ConditionsYield
With pyridine; dmap In dichloromethane at 20℃; Inert atmosphere;96%
4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

allyl-trimethyl-silane
762-72-1

allyl-trimethyl-silane

But-3-enoic acid 4-chloro-phenyl ester
121077-72-3

But-3-enoic acid 4-chloro-phenyl ester

Conditions
ConditionsYield
With aluminium trichloride In dichloromethane for 0.5h; Ambient temperature;95%
4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

Methyl 2-O-allyl-3,4-di-O-benzyl-β-D-glucopyranoside
331281-66-4

Methyl 2-O-allyl-3,4-di-O-benzyl-β-D-glucopyranoside

Methyl 2-O-allyl-3,4-di-O-benzyl-6-O-para-chlorophenylcarbonyl-β-D-glucopyranoside
331281-62-0

Methyl 2-O-allyl-3,4-di-O-benzyl-6-O-para-chlorophenylcarbonyl-β-D-glucopyranoside

Conditions
ConditionsYield
With pyridine; dmap In dichloromethane at 20℃; for 1h;95%
4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

(Z)-3-{3,4,5-trimethoxy-2-[2-(trifluoroacetylamino)ethyl]-phenyl}prop-2-enol
1332523-83-7

(Z)-3-{3,4,5-trimethoxy-2-[2-(trifluoroacetylamino)ethyl]-phenyl}prop-2-enol

4-chlorophenyl (Z)-3-{3,4,5-trimethoxy-2-[2-(trifluoroacetylamino)ethyl]phenyl}prop-2-enyl carbonate
1332523-92-8

4-chlorophenyl (Z)-3-{3,4,5-trimethoxy-2-[2-(trifluoroacetylamino)ethyl]phenyl}prop-2-enyl carbonate

Conditions
ConditionsYield
With pyridine In dichloromethane at 0℃; for 3h; Inert atmosphere;94%
4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

C63H60N3O6P3*3ClH

C63H60N3O6P3*3ClH

C30H24Cl3N3O12
1083072-42-7

C30H24Cl3N3O12

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine In dichloromethane at 20℃; Inert atmosphere; Cooling with ice;93%
4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

methyl 3,4-di-O-benzyl-2-O-levulinoyl-β-D-glucopyranoside
331281-76-6

methyl 3,4-di-O-benzyl-2-O-levulinoyl-β-D-glucopyranoside

Methyl 3,4-di-O-benzyl-6-O-para-chlorophenylcarbonyl-2-O-levulinyl-β-D-glucopyranoside

Methyl 3,4-di-O-benzyl-6-O-para-chlorophenylcarbonyl-2-O-levulinyl-β-D-glucopyranoside

Conditions
ConditionsYield
With pyridine; dmap In dichloromethane at 20℃; for 1h;91%
4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

4-fluoro-N-(indolin-6-yl)benzamide

4-fluoro-N-(indolin-6-yl)benzamide

4-chlorophenyl 6-(4-fluorobenzamido)indoline-1-carboxylate

4-chlorophenyl 6-(4-fluorobenzamido)indoline-1-carboxylate

Conditions
ConditionsYield
With triethylamine In acetonitrile at 60℃; under 750.075 Torr;91%
4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

triethyl phosphite
122-52-1

triethyl phosphite

diethyl 4-chlorophenoxycarbonylphosphonate
72305-96-5

diethyl 4-chlorophenoxycarbonylphosphonate

Conditions
ConditionsYield
90%
4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

ethyl 3,4,6-tri-O-benzyl-1-thio-β-D-glucopyranoside
180187-58-0

ethyl 3,4,6-tri-O-benzyl-1-thio-β-D-glucopyranoside

Thioethyl 3,4,6-tri-O-benzyl-2-O-para-chlorophenylcarbonyl-β-D-glucopyranoside
331281-74-4

Thioethyl 3,4,6-tri-O-benzyl-2-O-para-chlorophenylcarbonyl-β-D-glucopyranoside

Conditions
ConditionsYield
With pyridine; dmap In dichloromethane at 20℃; for 1h;90%
4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

Methyl 3,4-di-O-benzyl-2-O-para-methoxybenzyl-β-D-glucopyranoside
331281-67-5

Methyl 3,4-di-O-benzyl-2-O-para-methoxybenzyl-β-D-glucopyranoside

Methyl 3,4-di-O-benzyl-2-O-para-methoxybenzyl-6-O-para-chlorophenylcarbonyl-β-D-glucopyranoside
331281-63-1

Methyl 3,4-di-O-benzyl-2-O-para-methoxybenzyl-6-O-para-chlorophenylcarbonyl-β-D-glucopyranoside

Conditions
ConditionsYield
With pyridine; dmap In dichloromethane at 20℃; for 1h;90%
trans-4-(methylamino)cyclohexanecarboxylic acid methyl ester hydrochloride

trans-4-(methylamino)cyclohexanecarboxylic acid methyl ester hydrochloride

4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

trans-4-[(4-chloro-phenoxycarbonyl)-methyl-amino]-cyclohexane-carboxylic acid methyl ester

trans-4-[(4-chloro-phenoxycarbonyl)-methyl-amino]-cyclohexane-carboxylic acid methyl ester

Conditions
ConditionsYield
In pyridine at 0 - 20℃; for 22h;90%
(E)-2-Hexen-1-ol
928-95-0

(E)-2-Hexen-1-ol

4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

trans-hex-2-enyl 4-chlorophenyl carbonate
1419028-40-2

trans-hex-2-enyl 4-chlorophenyl carbonate

Conditions
ConditionsYield
With N,N,N,N,-tetramethylethylenediamine; triethylamine In dichloromethane at 0 - 20℃; for 0.5h;90%
4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

(1R,4aS,8aR)-1-((benzyloxy)methyl)octahydro-1H-pyrano[3,4-c]pyridin-7-ium chloride

(1R,4aS,8aR)-1-((benzyloxy)methyl)octahydro-1H-pyrano[3,4-c]pyridin-7-ium chloride

4-chlorophenyl (1R,4aS,8aR)-1-((benzyloxy)methyl)hexahydro-1H-pyrano[3,4-c]pyridine-7(3H)-carboxylate

4-chlorophenyl (1R,4aS,8aR)-1-((benzyloxy)methyl)hexahydro-1H-pyrano[3,4-c]pyridine-7(3H)-carboxylate

Conditions
ConditionsYield
With dmap; triethylamine In dichloromethane at 20℃; for 3h; Inert atmosphere;89%
4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

thymidine
50-89-5

thymidine

Carbonic acid 4-chloro-phenyl ester (2R,3S,5R)-3-hydroxy-5-(5-methyl-2,4-dioxo-3,4-dihydro-2H-pyrimidin-1-yl)-tetrahydro-furan-2-ylmethyl ester
259672-39-4

Carbonic acid 4-chloro-phenyl ester (2R,3S,5R)-3-hydroxy-5-(5-methyl-2,4-dioxo-3,4-dihydro-2H-pyrimidin-1-yl)-tetrahydro-furan-2-ylmethyl ester

Conditions
ConditionsYield
With pyridine88.3%
4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

2-<(methylamino)methyl>-4-nitrophenol
35039-53-3

2-<(methylamino)methyl>-4-nitrophenol

4-chlorophenyl N-(5-nitro-2-hydroxybenzyl)carbamate

4-chlorophenyl N-(5-nitro-2-hydroxybenzyl)carbamate

Conditions
ConditionsYield
With TEA In diethyl ether at 10 - 20℃; for 0.833333h;88%
4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

3-Phenylpropenol
104-54-1

3-Phenylpropenol

cinnamyl 4-chlorophenyl carbonate

cinnamyl 4-chlorophenyl carbonate

Conditions
ConditionsYield
With N,N,N,N,-tetramethylethylenediamine; triethylamine In dichloromethane at 0 - 20℃; for 0.5h;88%
4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

1-(4-phenylbutyl)-piperazine
97480-93-8

1-(4-phenylbutyl)-piperazine

4-(4-Phenylbutyl)piperazine-1-carboxylic acid 4-chlorophenyl ester
549510-70-5

4-(4-Phenylbutyl)piperazine-1-carboxylic acid 4-chlorophenyl ester

Conditions
ConditionsYield
86%
4,5-dichloro-2H-pyridazin-3-one
932-22-9

4,5-dichloro-2H-pyridazin-3-one

4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

4-chlorophenyl 4,5-dichloro-6-oxopyridazine-1(6H)-carboxylate

4-chlorophenyl 4,5-dichloro-6-oxopyridazine-1(6H)-carboxylate

Conditions
ConditionsYield
With triethylamine In dichloromethane at 5℃; for 0.166667h;86%
4-Chlorophenyl chloroformate
7693-45-0

4-Chlorophenyl chloroformate

methyl 2-O-benzoyl-3,4-di-O-benzyl-β-D-glucopyranoside
294637-56-2

methyl 2-O-benzoyl-3,4-di-O-benzyl-β-D-glucopyranoside

Methyl 2-O-benzoyl-3,4-di-O-benzyl-6-O-para-chlorophenylcarbonyl-β-D-glucopyranoside

Methyl 2-O-benzoyl-3,4-di-O-benzyl-6-O-para-chlorophenylcarbonyl-β-D-glucopyranoside

Conditions
ConditionsYield
With pyridine; dmap In dichloromethane at 20℃; for 1h;85%
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