{(C₂H₅)4N}⁽¹⁺⁾*{Cr(CO)5OC₆H₅}^(1-)={(C₂H₅)4N}{Cr(CO)5OC₆H₅}

Base Information

• Chemical Name: {(C₂H₅)4N}⁽¹⁺⁾*{Cr(CO)5OC₆H₅}^(1-)={(C₂H₅)4N}{Cr(CO)5OC₆H₅}
• CAS No.: 121918-63-6
• Molecular Formula: C₈H₂₀N*C₁₁H₅CrO₆
• Molecular Weight: 415.407
• Mol file: 121918-63-6.mol

Synonyms:{(C₂H₅)4N}⁽¹⁺⁾*{Cr(CO)5OC₆H₅}^(1-)={(C₂H₅)4N}{Cr(CO)5OC₆H₅}

Chemical Property of {(C₂H₅)4N}⁽¹⁺⁾*{Cr(CO)5OC₆H₅}^(1-)={(C₂H₅)4N}{Cr(CO)5OC₆H₅}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {(C₂H₅)4N}⁽¹⁺⁾*{Cr(CO)5OC₆H₅}^(1-)={(C₂H₅)4N}{Cr(CO)5OC₆H₅}

There total 2 articles about {(C₂H₅)4N}⁽¹⁺⁾*{Cr(CO)5OC₆H₅}^(1-)={(C₂H₅)4N}{Cr(CO)5OC₆H₅} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chromium(0) hexacarbonyl (199620-14-9,13007-92-6) → {(C2H5)4N}(1+)*{Cr(CO)5OC6H5}(1-)={(C2H5)4N}{Cr(CO)5OC6H5} (121918-63-6)

Guidance literature:

Multi-step reaction with 2 steps

1: neat (no solvent)

2: tetrahydrofuran

In tetrahydrofuran;

DOI:10.1021/ja00200a031

Reference yield:

pentacarbonyl(tetrahydrofuran)chromium(0) (15038-41-2) + tetraethylammonium phenolate (32580-85-1) → {(C2H5)4N}(1+)*{Cr(CO)5OC6H5}(1-)={(C2H5)4N}{Cr(CO)5OC6H5} (121918-63-6)

Guidance literature:

In tetrahydrofuran; under N2, addn. of a soln. of Cr(CO)5THF to the (Et4N)(OPh), stirring 5-10 min, 0°C; not isolated, detected by IR;

DOI:10.1021/ja00200a031

Reference yield:

{(C2H5)4N}(1+)*{Cr(CO)5OC6H5}(1-)={(C2H5)4N}{Cr(CO)5OC6H5} (121918-63-6) → chromium(0) hexacarbonyl (199620-14-9,13007-92-6)

Guidance literature:

With CO; In neat (no solvent); decomposition in the presence of CO for extended time periods;

DOI:10.1021/ja00200a031

upstream raw materials:

pentacarbonyl(tetrahydrofuran)chromium⁽⁰⁾

tetraethylammonium phenolate

chromium⁽⁰⁾ hexacarbonyl

Downstream raw materials:

(Et₄N) chromium pentacarbonyl phenyl thiocarbonate

(Et₄N) chromium pentacarbonyl phenyl dithiocarbonate

{Et₄N}{cis-Cr(CO)4(PMe₃)OPh}

{Et₄N}{cis-Cr(CO)4(P(OMe)3)OPh}