Ethanaminium, N,N,N-triethyl-, phenoxide

Base Information

• Chemical Name: Ethanaminium, N,N,N-triethyl-, phenoxide
• CAS No.: 32580-85-1
• Molecular Formula: C6H5O*C8H20N
• Molecular Weight: 223.359
• Mol file: 32580-85-1.mol

Synonyms:Ethanaminium, N,N,N-triethyl-, phenoxide

Chemical Property of Ethanaminium, N,N,N-triethyl-, phenoxide

Chemical Property:

• PSA: 23.06000
• LogP: 3.71320

Purity/Quality:

99.0%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Ethanaminium, N,N,N-triethyl-, phenoxide

There total 3 articles about Ethanaminium, N,N,N-triethyl-, phenoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.8%

tetraethylammonium hydroxide (77-98-5) + phenol (108-95-2,27073-41-2) → tetraethylammonium phenolate (32580-85-1)

Guidance literature:

In water; acetone; for 0.5h; Schlenk technique; Inert atmosphere;

DOI:10.1021/jacs.9b00466

Reference yield: 86.0%

tetraethylammonium hydroxide (77-98-5) + phenol (108-95-2,27073-41-2) → C14H25NO (32580-85-1)

Guidance literature:

In methanol; at 65 ℃; for 2h;

DOI:10.1021/ja00200a031

Reference yield: 8.1%

tetraethylammonium chloride (56-34-8) + phenol (108-95-2,27073-41-2) → tetraethylammonium phenolate (32580-85-1)

Guidance literature:

With sodium; 1.) Et₂O, 2.) MeCN-THF;

DOI:10.1021/ja00341a029

upstream raw materials:

tetraethylammonium hydroxide

phenol

tetraethylammonium chloride

tetraethylammonium hydroxide

Downstream raw materials:

{Et4N}4{Cr4(CO)12(μOPh)4}

3(C₂H₅)4N⁽¹⁺⁾*MoFe₃S₄(SC₆H₄Cl)3(C₆H₂(C₂H₅)2O₂)OC₆H₅^(3-)

{Et₄N}4{W₄(CO)12(OPh)4}

{(C₂H₅)4N}⁽¹⁺⁾*{W(CO)5COOC₆H₅}^(1-)={(C₂H₅)4N}{W(CO)5COOC₆H₅}

Refernces

• 1、 Darensbourg, Donald J.,Sanchez, Kathryn M.,Reibenspies, Joseph H.,Rheingold, Arnold L.. "Synthesis, Structure, and Reactivity of Zerovalent Group 6 Metal Pentacarbonyl Aryl Oxide Complexes. Reactions with Carbon Dioxide". . p. 7094 - 7103. Retrieved 2007/10/02.