1,2-O-(1-Methylethylidene)-3,4,5-tris-O-(phenylmethyl)-6-O-<2-(p-toluenesulfonyloxy)ethyl>-D,L-myo-inositol

Base Information

Chemical Name:1,2-O-(1-Methylethylidene)-3,4,5-tris-O-(phenylmethyl)-6-O-<2-(p-toluenesulfonyloxy)ethyl>-D,L-myo-inositol
CAS No.:132628-31-0
Molecular Formula:C₃₉H₄₄O₉S
Molecular Weight:688.839
Hs Code.:

Synonyms:1,2-O-(1-Methylethylidene)-3,4,5-tris-O-(phenylmethyl)-6-O-<2-(p-toluenesulfonyloxy)ethyl>-D,L-myo-inositol

Suppliers and Price of 1,2-O-(1-Methylethylidene)-3,4,5-tris-O-(phenylmethyl)-6-O-<2-(p-toluenesulfonyloxy)ethyl>-D,L-myo-inositol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1,2-O-(1-Methylethylidene)-3,4,5-tris-O-(phenylmethyl)-6-O-<2-(p-toluenesulfonyloxy)ethyl>-D,L-myo-inositol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1,2-O-(1-Methylethylidene)-3,4,5-tris-O-(phenylmethyl)-6-O-<2-(p-toluenesulfonyloxy)ethyl>-D,L-myo-inositol

There total 6 articles about 1,2-O-(1-Methylethylidene)-3,4,5-tris-O-(phenylmethyl)-6-O-<2-(p-toluenesulfonyloxy)ethyl>-D,L-myo-inositol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 4124-41-8
p-toluenesulfonylanhydride

: 132628-35-4
2-((3aS,4R,5S,6S,7R,7aR)-5,6,7-Tris-benzyloxy-2,2-dimethyl-hexahydro-benzo[1,3]dioxol-4-yloxy)-ethanol

: 132628-31-0
1,2-O-(1-Methylethylidene)-3,4,5-tris-O-(phenylmethyl)-6-O-<2-(p-toluenesulfonyloxy)ethyl>-D,L-myo-inositol

Guidance literature:: With pyridine; In dichloromethane; 1.) 0 deg C, 30 min, 2.) room temperature, 1 h;
DOI:10.1016/0040-4020(91)80004-L

Reference yield:

: 100-39-0
benzyl bromide

: 132628-31-0
1,2-O-(1-Methylethylidene)-3,4,5-tris-O-(phenylmethyl)-6-O-<2-(p-toluenesulfonyloxy)ethyl>-D,L-myo-inositol

Guidance literature:: Multi-step reaction with 5 steps

1: 96 percent / potassium tert-butoxide, 18-crown-6 / tetrahydrofuran / 1 h

2: OsO₄, N-methylmorpholine-N-oxide / acetone; H₂O

3: NaIO₄ / dioxane; H₂O / 25 h

4: NaBH₄ / tetrahydrofuran; propan-2-ol / 1 h / 0 deg C to room temperature

5: 100 percent / pyridine / CH₂Cl₂ / 1.) 0 deg C, 30 min, 2.) room temperature, 1 h

With pyridine; sodium tetrahydroborate; sodium periodate; osmium(VIII) oxide; 18-crown-6 ether; potassium tert-butylate; 4-methylmorpholine N-oxide; In tetrahydrofuran; 1,4-dioxane; dichloromethane; water; isopropyl alcohol; acetone;
DOI:10.1016/0040-4020(91)80004-L

Reference yield:

: 131147-11-0,132697-47-3
(±)-2,3-O-isopropylidene-1,5,6-tri-O-benzyl-4-O-allyl-myo-inositol

: 132628-31-0
1,2-O-(1-Methylethylidene)-3,4,5-tris-O-(phenylmethyl)-6-O-<2-(p-toluenesulfonyloxy)ethyl>-D,L-myo-inositol

Guidance literature:: Multi-step reaction with 4 steps

1: OsO₄, N-methylmorpholine-N-oxide / acetone; H₂O

2: NaIO₄ / dioxane; H₂O / 25 h

3: NaBH₄ / tetrahydrofuran; propan-2-ol / 1 h / 0 deg C to room temperature

4: 100 percent / pyridine / CH₂Cl₂ / 1.) 0 deg C, 30 min, 2.) room temperature, 1 h

With pyridine; sodium tetrahydroborate; sodium periodate; osmium(VIII) oxide; 4-methylmorpholine N-oxide; In tetrahydrofuran; 1,4-dioxane; dichloromethane; water; isopropyl alcohol; acetone;
DOI:10.1016/0040-4020(91)80004-L