{(1,8-bis{5-(2,8,13,17-tetraethyl-3,7,12,18-tetramethyl)porphyrin}biphenylene tetra-anion)Ru₂(triphenylphosphine)2}

Base Information

• Chemical Name: {(1,8-bis{5-(2,8,13,17-tetraethyl-3,7,12,18-tetramethyl)porphyrin}biphenylene tetra-anion)Ru₂(triphenylphosphine)2}
• CAS No.: 107081-53-8
• Molecular Formula: C₁₁₂H₁₀₆N₈P₂Ru₂
• Molecular Weight: 1828.21
• Mol file: 107081-53-8.mol

Synonyms:{(1,8-bis{5-(2,8,13,17-tetraethyl-3,7,12,18-tetramethyl)porphyrin}biphenylene tetra-anion)Ru₂(triphenylphosphine)2}

Chemical Property of {(1,8-bis{5-(2,8,13,17-tetraethyl-3,7,12,18-tetramethyl)porphyrin}biphenylene tetra-anion)Ru₂(triphenylphosphine)2}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {(1,8-bis{5-(2,8,13,17-tetraethyl-3,7,12,18-tetramethyl)porphyrin}biphenylene tetra-anion)Ru₂(triphenylphosphine)2}

There total 2 articles about {(1,8-bis{5-(2,8,13,17-tetraethyl-3,7,12,18-tetramethyl)porphyrin}biphenylene tetra-anion)Ru₂(triphenylphosphine)2} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

{(1,8-bis{5-(2,8,13,17-tetraethyl-3,7,12,18-tetramethyl)porphyrin}biphenylene tetra-anion)Ru2(CO)2(MeOH)2} (106960-14-9) → {(1,8-bis{5-(2,8,13,17-tetraethyl-3,7,12,18-tetramethyl)porphyrin}biphenylene tetra-anion)Ru2(triphenylphosphine)2} (107081-53-8)

Guidance literature:

With triphenylphosphine; In toluene; byproducts: triphenylphosphine oxide; suspn. of Ru-complex in refluxing toluene (drybox), addn. of PPh3, heating for 8 days (monitoring of react. by UV); column chromy. (alumina, neutral, activity I, toluene as eluent), evapn. to dryness, sublimation (high vac., 5E-6 torr, 50°C); elem. anal.;

Reference yield:

Ru2(1,8-bis[5-(2,8,13,17-tetraethyl-3,7,12,18-tetramethyl)porphinato]biphenylene) (106935-77-7) → {(1,8-bis{5-(2,8,13,17-tetraethyl-3,7,12,18-tetramethyl)porphyrin}biphenylene tetra-anion)Ru2(triphenylphosphine)2} (107081-53-8)

Guidance literature:

With triphenylphosphine; In not given;

DOI:10.1039/c39860001711

Reference yield: 90.0%

{(1,8-bis{5-(2,8,13,17-tetraethyl-3,7,12,18-tetramethyl)porphyrin}biphenylene tetra-anion)Ru2(triphenylphosphine)2} (107081-53-8) → Ru2DPB(triphenylphosphine)2(μ-hydrazine) (107081-49-2)

Guidance literature:

With hydrazine; In toluene; dissolution of Ru-complex in toluene (drybox), addn. of 2 drops of N2H4, stirring for 5 h at room temp.; column chromy. (alumina, neutral, activity I) evapn. to dryness, drying under high vac.; elem. anal.;

upstream raw materials:

Ru₂(1,8-bis[5-(2,8,13,17-tetraethyl-3,7,12,18-tetramethyl)porphinato]biphenylene)

{(1,8-bis{5-(2,8,13,17-tetraethyl-3,7,12,18-tetramethyl)porphyrin}biphenylene tetra-anion)Ru₂(CO)2(MeOH)2}

Downstream raw materials:

Ru2DPB(triphenylphosphine)2(μ-hydrazine)