[carbonic acid-(4-methoxy-phenyl ester)]-(4-nitro-benzoic acid )-anhydride

Base Information

• Chemical Name: [carbonic acid-(4-methoxy-phenyl ester)]-(4-nitro-benzoic acid )-anhydride
• CAS No.: 81372-24-9
• Molecular Formula: C₁₅H₁₁NO₇
• Molecular Weight: 317.255
• Mol file: 81372-24-9.mol

Synonyms:[carbonic acid-(4-methoxy-phenyl ester)]-(4-nitro-benzoic acid )-anhydride

Chemical Property of [carbonic acid-(4-methoxy-phenyl ester)]-(4-nitro-benzoic acid )-anhydride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of [carbonic acid-(4-methoxy-phenyl ester)]-(4-nitro-benzoic acid )-anhydride

There total 5 articles about [carbonic acid-(4-methoxy-phenyl ester)]-(4-nitro-benzoic acid )-anhydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

p-methoxybenzoyl p-nitrobenzoyl peroxide (1829-89-6) → p-nitrobenzoic anhydride (902-47-6) + 4-methoxyphenyl 4-nitrobenzoate (13245-59-5) + [carbonic acid-(4-methoxy-phenyl ester)]-(4-nitro-benzoic acid )-anhydride (81372-24-9) + 4-methoxy-phenol (150-76-5) + 4-nitro-benzoic acid (62-23-7)

Guidance literature:

silica gel; In benzene; at 21 ℃; for 0.5h; Product distribution; Rate constant; var. solvent and temp., reaction in the absence of silica and with irradiation;

DOI:10.1021/jo00133a010

Reference yield:

p-methoxybenzoyl p-nitrobenzoyl peroxide (1829-89-6) → [carbonic acid-(4-methoxy-phenyl ester)]-(4-nitro-benzoic acid )-anhydride (81372-24-9)

Guidance literature:

With thionyl chloride;

DOI:10.1021/ja01157a019

Reference yield:

4-methoxy-benzoyl chloride (100-07-2) → [carbonic acid-(4-methoxy-phenyl ester)]-(4-nitro-benzoic acid )-anhydride (81372-24-9)

Guidance literature:

Multi-step reaction with 2 steps

1: aqueous Na₂CO₃

2: SOCl₂

With thionyl chloride; sodium carbonate;

DOI:10.1021/ja01157a019

upstream raw materials:

p-methoxybenzoyl p-nitrobenzoyl peroxide

thionyl chloride

4-methoxy-benzoyl chloride