methyl-[O⁴,O⁶-((R)-benzylidene)-O³-trifluoroacetyl-α-D-glucopyranoside]

Base Information

• Chemical Name: methyl-[O⁴,O⁶-((R)-benzylidene)-O³-trifluoroacetyl-α-D-glucopyranoside]
• CAS No.: 18031-56-6
• Molecular Formula: C₁₆H₁₇F₃O₇
• Molecular Weight: 378.302
• Mol file: 18031-56-6.mol

Synonyms:methyl-[O⁴,O⁶-((R)-benzylidene)-O³-trifluoroacetyl-α-D-glucopyranoside]

Chemical Property of methyl-[O⁴,O⁶-((R)-benzylidene)-O³-trifluoroacetyl-α-D-glucopyranoside]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl-[O⁴,O⁶-((R)-benzylidene)-O³-trifluoroacetyl-α-D-glucopyranoside]

There total 2 articles about methyl-[O⁴,O⁶-((R)-benzylidene)-O³-trifluoroacetyl-α-D-glucopyranoside] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methyl-[O4,O6-((R)-benzylidene)-O2,O3-bis-trifluoroacetyl-α-D-glucopyranoside] (2647-10-1) → methyl-[O4,O6-((R)-benzylidene)-O3-trifluoroacetyl-α-D-glucopyranoside] (18031-56-6)

Guidance literature:

With methanol; tetrachloromethane;

Reference yield:

sodium 2,2,2-trifluoroacetate (2923-18-4) + trifluoroacetic anhydride (407-25-0) + 4,6-O-benzylidene-1-O-methyl-α-D-glucopyranoside (3162-96-7) → methyl-[O4,O6-((R)-benzylidene)-O3-trifluoroacetyl-α-D-glucopyranoside] (18031-56-6) + methyl-[O4,O6-((R)-benzylidene)-O2,O3-bis-trifluoroacetyl-α-D-glucopyranoside] (2647-10-1)

Guidance literature:

Reference yield:

methyl-[O4,O6-((R)-benzylidene)-O3-trifluoroacetyl-α-D-glucopyranoside] (18031-56-6) → methyl 2,3-anhydro-4,6-O-benzilidene-α-D-mannopyranoside (3150-15-0,3150-16-1,3257-59-8,14187-71-4,15384-57-3,19465-13-5,32976-15-1,52885-37-7,53270-02-3,53270-03-4,65391-11-9,65391-12-0,66537-92-6,67226-04-4,71184-14-0,86420-78-2,86420-79-3,91177-51-4,91177-52-5,117708-93-7,120408-72-2,2880-96-8)

Guidance literature:

Multi-step reaction with 3 steps

1: pyridine / Behandeln des Reaktionsprodukts mit Aethanol

2: pyridine

3: sodium methylate; methanol

With pyridine; methanol; sodium methylate;

upstream raw materials:

methyl-[O⁴,O⁶-((R)-benzylidene)-O²,O³-bis-trifluoroacetyl-α-D-glucopyranoside]

sodium 2,2,2-trifluoroacetate

trifluoroacetic anhydride

4,6-O-benzylidene-1-O-methyl-α-D-glucopyranoside

Downstream raw materials:

methyl 2-O-benzoyl-4,6-di-O-benzylidene-α-D-glucopyranoside

methyl 3-O-benzoyl-4,6-O-benzylidene-α-D-glucopyranoside

methyl 3-O-acetyl-4,6-O-benzylidene-α-D-glucopyranoside

methyl-[O⁴,O⁶-((R)-benzylidene)-O²-(toluene-4-sulfonyl)-O³-trifluoroacetyl-α-D-glucopyranoside]