C₃₅H₅₉ClO₆Si₂

Base Information

Chemical Name:C₃₅H₅₉ClO₆Si₂
CAS No.:1333237-65-2
Molecular Formula:C₃₅H₅₉ClO₆Si₂
Molecular Weight:667.474
Hs Code.:

C<sub>35</sub>H<sub>59</sub>ClO<sub>6</sub>Si<sub>2</sub>

Synonyms:C₃₅H₅₉ClO₆Si₂

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Chemical Property of C₃₅H₅₉ClO₆Si₂

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Technology Process of C₃₅H₅₉ClO₆Si₂

There total 20 articles about C₃₅H₅₉ClO₆Si₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: 1333237-04-9
C₁₆H₂₈Cl₂O₅Si

: 1333237-00-5
((4R,5S)-4-(benzyloxy)-5-(tert-butyldimethylsilyloxy)hexyl)triphenylphosphonium iodide

: 1333237-65-2
C₃₅H₅₉ClO₆Si₂

: 1333237-02-7
((2S,3S)-3-((1R,2S,4S,9R,10S,z)-9-(benzyloxy)-4,10-bis(tert-butyldimethylsilyloxy)-1,2-dichloroundec-5-enyl)oxiran-2-yl)methyl acetate

Guidance literature:: ((4R,5S)-4-(benzyloxy)-5-(tert-butyldimethylsilyloxy)hexyl)triphenylphosphonium iodide; With potassium hexamethylsilazane; In tetrahydrofuran; at 0 ℃; for 0.333333h; Inert atmosphere;

C₁₆H₂₈Cl₂O₅Si; In tetrahydrofuran; at -78 - 0 ℃; for 1h; stereoselective reaction; Inert atmosphere;
DOI:10.1002/anie.201102521

Reference yield:

: 1333236-45-5
(4R,5S,E)-4,5-dichloro-6-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)hex-2-en-1-ol

: 1333237-65-2
C₃₅H₅₉ClO₆Si₂

: 1333237-02-7
((2S,3S)-3-((1R,2S,4S,9R,10S,z)-9-(benzyloxy)-4,10-bis(tert-butyldimethylsilyloxy)-1,2-dichloroundec-5-enyl)oxiran-2-yl)methyl acetate

Guidance literature:: Multi-step reaction with 8 steps

1.1: dmap; triethylamine / dichloromethane / 0.17 h / 0 °C / Inert atmosphere

2.1: AD-mix-β; methanesulfonamide; water / tert-butyl alcohol / 46 h / 0 - 4 °C / Inert atmosphere

3.1: 1,4-diaza-bicyclo[2.2.2]octane; trifluoromethylsulfonic anhydride / dichloromethane / 19 h / -78 - 20 °C / Inert atmosphere

4.1: camphor-10-sulfonic acid / methanol / 2 h / 20 °C / Inert atmosphere

5.1: 2,6-dimethylpyridine / dichloromethane / 2.5 h / -78 - -15 °C / Inert atmosphere

6.1: pyridine; pyridine hydrofluoride / tetrahydrofuran / 15 h / 0 - 4 °C / Inert atmosphere

7.1: Dess-Martin periodane / dichloromethane / 0.75 h / 20 °C / Inert atmosphere

8.1: potassium hexamethylsilazane / tetrahydrofuran / 0.33 h / 0 °C / Inert atmosphere

8.2: 1 h / -78 - 0 °C / Inert atmosphere

With pyridine; 1,4-diaza-bicyclo[2.2.2]octane; 2,6-dimethylpyridine; dmap; methanesulfonamide; pyridine hydrofluoride; trifluoromethylsulfonic anhydride; AD-mix-β; camphor-10-sulfonic acid; water; potassium hexamethylsilazane; Dess-Martin periodane; triethylamine; In tetrahydrofuran; methanol; dichloromethane; tert-butyl alcohol; 2.1: Sharpless dihydroxylation / 7.1: Dess-Martin oxidation / 8.1: Wittig reaction / 8.2: Wittig reaction;
DOI:10.1002/anie.201102521

Reference yield:

: C₁₃H₂₀Cl₂O₄

: 1333237-65-2
C₃₅H₅₉ClO₆Si₂

: 1333237-02-7
((2S,3S)-3-((1R,2S,4S,9R,10S,z)-9-(benzyloxy)-4,10-bis(tert-butyldimethylsilyloxy)-1,2-dichloroundec-5-enyl)oxiran-2-yl)methyl acetate

Guidance literature:: Multi-step reaction with 9 steps

1.1: diisobutylaluminium hydride / toluene / 0.5 h / 0 °C / Inert atmosphere

1.2: 0 °C / Inert atmosphere

2.1: dmap; triethylamine / dichloromethane / 0.17 h / 0 °C / Inert atmosphere

3.1: AD-mix-β; methanesulfonamide; water / tert-butyl alcohol / 46 h / 0 - 4 °C / Inert atmosphere

4.1: 1,4-diaza-bicyclo[2.2.2]octane; trifluoromethylsulfonic anhydride / dichloromethane / 19 h / -78 - 20 °C / Inert atmosphere

5.1: camphor-10-sulfonic acid / methanol / 2 h / 20 °C / Inert atmosphere

6.1: 2,6-dimethylpyridine / dichloromethane / 2.5 h / -78 - -15 °C / Inert atmosphere

7.1: pyridine; pyridine hydrofluoride / tetrahydrofuran / 15 h / 0 - 4 °C / Inert atmosphere

8.1: Dess-Martin periodane / dichloromethane / 0.75 h / 20 °C / Inert atmosphere

9.1: potassium hexamethylsilazane / tetrahydrofuran / 0.33 h / 0 °C / Inert atmosphere

9.2: 1 h / -78 - 0 °C / Inert atmosphere

With pyridine; 1,4-diaza-bicyclo[2.2.2]octane; 2,6-dimethylpyridine; dmap; methanesulfonamide; pyridine hydrofluoride; trifluoromethylsulfonic anhydride; AD-mix-β; camphor-10-sulfonic acid; water; potassium hexamethylsilazane; diisobutylaluminium hydride; Dess-Martin periodane; triethylamine; In tetrahydrofuran; methanol; dichloromethane; toluene; tert-butyl alcohol; 3.1: Sharpless dihydroxylation / 8.1: Dess-Martin oxidation / 9.1: Wittig reaction / 9.2: Wittig reaction;
DOI:10.1002/anie.201102521