3-methoxy-6,6-dimethyl-2-[4-(1-methylethyl)-2,3,5-trimethoxyphenylmethyl]-2-cyclohexenone

Base Information

Chemical Name:3-methoxy-6,6-dimethyl-2-[4-(1-methylethyl)-2,3,5-trimethoxyphenylmethyl]-2-cyclohexenone
CAS No.:156723-09-0
Molecular Formula:C₂₂H₃₂O₅
Molecular Weight:376.493
Hs Code.:

Synonyms:3-methoxy-6,6-dimethyl-2-[4-(1-methylethyl)-2,3,5-trimethoxyphenylmethyl]-2-cyclohexenone

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Chemical Property of 3-methoxy-6,6-dimethyl-2-[4-(1-methylethyl)-2,3,5-trimethoxyphenylmethyl]-2-cyclohexenone

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Technology Process of 3-methoxy-6,6-dimethyl-2-[4-(1-methylethyl)-2,3,5-trimethoxyphenylmethyl]-2-cyclohexenone

There total 10 articles about 3-methoxy-6,6-dimethyl-2-[4-(1-methylethyl)-2,3,5-trimethoxyphenylmethyl]-2-cyclohexenone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 77-78-1
dimethyl sulfate

: 156723-08-9
4,4-dimethyl-2-[4-(1-methylethyl)-2,3,5-trimethoxyphenyl-methyl]-1,3-cyclohexanedione

: 156723-09-0
3-methoxy-6,6-dimethyl-2-[4-(1-methylethyl)-2,3,5-trimethoxyphenylmethyl]-2-cyclohexenone

Guidance literature:: 4,4-dimethyl-2-[4-(1-methylethyl)-2,3,5-trimethoxyphenyl-methyl]-1,3-cyclohexanedione; With sodium hydride; In N,N-dimethyl-formamide; at 0 - 20 ℃; for 1h; Inert atmosphere;

dimethyl sulfate; In N,N-dimethyl-formamide; at 20 ℃; for 12h; Inert atmosphere;
DOI:10.1016/j.tet.2011.09.072

Reference yield: 94.0%

: 90611-61-3
3-methoxy-6,6-dimethylcyclohex-2-en-1-one

: 156723-07-8
2-(1-methylethyl)-1,3,4-trimethoxy-5-(bromomethyl)benzene

: 156723-09-0
3-methoxy-6,6-dimethyl-2-[4-(1-methylethyl)-2,3,5-trimethoxyphenylmethyl]-2-cyclohexenone

Guidance literature:: 3-methoxy-6,6-dimethylcyclohex-2-en-1-one; With lithium diisopropyl amide; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; at -78 - 0 ℃; for 10h; Inert atmosphere;

2-(1-methylethyl)-1,3,4-trimethoxy-5-(bromomethyl)benzene; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; at 0 - 20 ℃; for 12h; Inert atmosphere;
DOI:10.1016/j.tet.2011.09.072

Reference yield:

: 562-46-9
4,4-dimethylcyclohexane-1,3-dione

: 156723-09-0
3-methoxy-6,6-dimethyl-2-[4-(1-methylethyl)-2,3,5-trimethoxyphenylmethyl]-2-cyclohexenone

Guidance literature:: Multi-step reaction with 2 steps

1: 89 percent / 20percent aq. K₂CO₃, KI

2: 1.) NaH / 1.) DMF

With sodium hydride; potassium carbonate; potassium iodide;
DOI:10.1021/ja00090a050