2-Diazo-malonic acid ethyl ester 1-((Z)-3-phenylsulfanyl-propenyl)-hexyl ester

Base Information

Chemical Name:2-Diazo-malonic acid ethyl ester 1-((Z)-3-phenylsulfanyl-propenyl)-hexyl ester
CAS No.:122663-87-0
Molecular Formula:C₂₀H₂₆N₂O₄S
Molecular Weight:390.503
Hs Code.:

Synonyms:2-Diazo-malonic acid ethyl ester 1-((Z)-3-phenylsulfanyl-propenyl)-hexyl ester

Suppliers and Price of 2-Diazo-malonic acid ethyl ester 1-((Z)-3-phenylsulfanyl-propenyl)-hexyl ester

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-Diazo-malonic acid ethyl ester 1-((Z)-3-phenylsulfanyl-propenyl)-hexyl ester

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of 2-Diazo-malonic acid ethyl ester 1-((Z)-3-phenylsulfanyl-propenyl)-hexyl ester

There total 4 articles about 2-Diazo-malonic acid ethyl ester 1-((Z)-3-phenylsulfanyl-propenyl)-hexyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 122663-98-3
Malonic acid ethyl ester 1-((Z)-3-phenylsulfanyl-propenyl)-hexyl ester

: 122663-87-0
2-Diazo-malonic acid ethyl ester 1-((Z)-3-phenylsulfanyl-propenyl)-hexyl ester

Guidance literature:: With 4-toluenesulfonyl azide; triethylamine; In acetonitrile; at 45 ℃; for 40h;
DOI:10.1016/S0040-4039(00)99523-6

Reference yield:

: 5651-88-7
phenyl propargyl sulfide

: 122663-87-0
2-Diazo-malonic acid ethyl ester 1-((Z)-3-phenylsulfanyl-propenyl)-hexyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) ethylmagnesium bromide / 2.) THF, 0 deg C

2: 80 percent / pyridine / tetrahydrofuran / 3 h / 0 °C

3: 82 percent / H₂ / 5percent Pd-BaSO₄ / methanol

4: 98 percent / p-toluenesulfonyl azide, triethylamine / acetonitrile / 40 h / 45 °C

With pyridine; 4-toluenesulfonyl azide; ethylmagnesium bromide; hydrogen; triethylamine; palladium on barium sulfate; In tetrahydrofuran; methanol; acetonitrile;
DOI:10.1016/S0040-4039(00)99523-6

Reference yield:

: 122663-91-6
1-Phenylsulfanyl-non-2-yn-4-ol

: 122663-87-0
2-Diazo-malonic acid ethyl ester 1-((Z)-3-phenylsulfanyl-propenyl)-hexyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 80 percent / pyridine / tetrahydrofuran / 3 h / 0 °C

2: 82 percent / H₂ / 5percent Pd-BaSO₄ / methanol

3: 98 percent / p-toluenesulfonyl azide, triethylamine / acetonitrile / 40 h / 45 °C

With pyridine; 4-toluenesulfonyl azide; hydrogen; triethylamine; palladium on barium sulfate; In tetrahydrofuran; methanol; acetonitrile;
DOI:10.1016/S0040-4039(00)99523-6