[7-(tert-butyldimethylsilanyloxy)dodeca-3,5-dienyl]triphenylphosphonium iodide

Base Information

Chemical Name:[7-(tert-butyldimethylsilanyloxy)dodeca-3,5-dienyl]triphenylphosphonium iodide
CAS No.:1295575-59-5
Molecular Formula:C₃₆H₅₀OPSi*I
Molecular Weight:684.756
Hs Code.:

Synonyms:[7-(tert-butyldimethylsilanyloxy)dodeca-3,5-dienyl]triphenylphosphonium iodide

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [7-(tert-butyldimethylsilanyloxy)dodeca-3,5-dienyl]triphenylphosphonium iodide

Chemical Property:

Purity/Quality:

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Technology Process of [7-(tert-butyldimethylsilanyloxy)dodeca-3,5-dienyl]triphenylphosphonium iodide

There total 8 articles about [7-(tert-butyldimethylsilanyloxy)dodeca-3,5-dienyl]triphenylphosphonium iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 1295575-58-4
7-(tert-butyldimethylsilanyloxy)-1-iodo-dodeca-3,5-dien

: 603-35-0
triphenylphosphine

: 1295575-59-5
[7-(tert-butyldimethylsilanyloxy)dodeca-3,5-dienyl]triphenylphosphonium iodide

Guidance literature:: In acetonitrile; at 65 ℃; for 48h;
DOI:10.1016/j.bmcl.2011.01.032

Reference yield:

: 1295575-54-0
tert-butyl-[1-(2,2-dimethyl-[1,3]dioxolan-4-yl)-hex-3-enyloxy]dimethyl silane

: 1295575-59-5
[7-(tert-butyldimethylsilanyloxy)dodeca-3,5-dienyl]triphenylphosphonium iodide

Guidance literature:: Multi-step reaction with 7 steps

1.1: 5% Pd(II)/C(eggshell); hydrogen / ethanol / 5 h / 20 °C / Inert atmosphere

2.1: periodic acid / tetrahydrofuran; diethyl ether / 12 h / 20 °C / Inert atmosphere

3.1: benzene / 12 h / 65 °C

4.1: N,N,N,N,N,N-hexamethylphosphoric triamide; lithium hexamethyldisilazane / tetrahydrofuran / 0.5 h / -78 °C

4.2: -78 - 20 °C

5.1: acetic acid / tetrahydrofuran; water / 8 h / 20 °C

6.1: 1H-imidazole; iodine; triphenylphosphine / dichloromethane / 3 h / 0 °C

7.1: acetonitrile / 48 h / 65 °C

With 1H-imidazole; N,N,N,N,N,N-hexamethylphosphoric triamide; 5% Pd(II)/C(eggshell); hydrogen; iodine; acetic acid; periodic acid; triphenylphosphine; lithium hexamethyldisilazane; In tetrahydrofuran; diethyl ether; ethanol; dichloromethane; water; acetonitrile; benzene;
DOI:10.1016/j.bmcl.2011.01.032

Reference yield:

: 1295575-56-2
7-(tert-butyldimethylsilanyloxy)-1-tributylsilanyloxy-dodeca-3,5-diene

: 1295575-59-5
[7-(tert-butyldimethylsilanyloxy)dodeca-3,5-dienyl]triphenylphosphonium iodide

Guidance literature:: Multi-step reaction with 3 steps

1: acetic acid / tetrahydrofuran; water / 8 h / 20 °C

2: 1H-imidazole; iodine; triphenylphosphine / dichloromethane / 3 h / 0 °C

3: acetonitrile / 48 h / 65 °C

With 1H-imidazole; iodine; acetic acid; triphenylphosphine; In tetrahydrofuran; dichloromethane; water; acetonitrile;
DOI:10.1016/j.bmcl.2011.01.032