(3R,5S)-3-(tert-butyldiphenylsilanyloxy)-5-(4-methoxybenzyloxy)oct-7-oxoheptanethioic acid S-tert-butyl ester

Base Information

Chemical Name:(3R,5S)-3-(tert-butyldiphenylsilanyloxy)-5-(4-methoxybenzyloxy)oct-7-oxoheptanethioic acid S-tert-butyl ester
CAS No.:910046-62-7
Molecular Formula:C₃₅H₄₆O₅SSi
Molecular Weight:606.899
Hs Code.:

Synonyms:(3R,5S)-3-(tert-butyldiphenylsilanyloxy)-5-(4-methoxybenzyloxy)oct-7-oxoheptanethioic acid S-tert-butyl ester

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Chemical Property of (3R,5S)-3-(tert-butyldiphenylsilanyloxy)-5-(4-methoxybenzyloxy)oct-7-oxoheptanethioic acid S-tert-butyl ester

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Technology Process of (3R,5S)-3-(tert-butyldiphenylsilanyloxy)-5-(4-methoxybenzyloxy)oct-7-oxoheptanethioic acid S-tert-butyl ester

There total 8 articles about (3R,5S)-3-(tert-butyldiphenylsilanyloxy)-5-(4-methoxybenzyloxy)oct-7-oxoheptanethioic acid S-tert-butyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 910046-77-4
3-(tert-butyl-diphenyl-silanyloxy)-7,8-dihydroxy-5-(4-methoxy-benzyloxy)-octanethioic acid S-tert-butyl ester

: 910046-62-7
(3R,5S)-3-(tert-butyldiphenylsilanyloxy)-5-(4-methoxybenzyloxy)oct-7-oxoheptanethioic acid S-tert-butyl ester

Guidance literature:: With lead(IV) acetate; In benzene; at 20 ℃; for 1h;
DOI:10.1021/ol061173h

Reference yield:

: 910046-60-5
(3R,5S)-3-hydroxy-5-(4-methoxybenzyloxy)oct-7-enethioic acid S-tert-butyl ester

: 910046-62-7
(3R,5S)-3-(tert-butyldiphenylsilanyloxy)-5-(4-methoxybenzyloxy)oct-7-oxoheptanethioic acid S-tert-butyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 92 percent / imidazole / dimethylformamide / 24 h / 20 °C

2: 4-methylmorpholine-N-oxide; OsO₄ / 2-methyl-propan-2-ol; tetrahydrofuran; H₂O / 14 h / 20 °C

3: 991 mg / Pb(OAc)4 / benzene / 1 h / 20 °C

With 1H-imidazole; lead(IV) acetate; osmium(VIII) oxide; 4-methylmorpholine N-oxide; In tetrahydrofuran; water; N,N-dimethyl-formamide; tert-butyl alcohol; benzene;
DOI:10.1016/j.tetlet.2006.09.094

Reference yield:

: 910046-76-3
(3R,5S)-3-(tert-butyldiphenylsilanyloxy)-5-(4-methoxybenzyloxy)oct-7-enethioic acid S-tert-butyl ester

: 910046-62-7
(3R,5S)-3-(tert-butyldiphenylsilanyloxy)-5-(4-methoxybenzyloxy)oct-7-oxoheptanethioic acid S-tert-butyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 4-methylmorpholine-N-oxide; OsO₄ / 2-methyl-propan-2-ol; tetrahydrofuran; H₂O / 14 h / 20 °C

2: 991 mg / Pb(OAc)4 / benzene / 1 h / 20 °C

With lead(IV) acetate; osmium(VIII) oxide; 4-methylmorpholine N-oxide; In tetrahydrofuran; water; tert-butyl alcohol; benzene;
DOI:10.1016/j.tetlet.2006.09.094