4-oxobicyclo[3.2.1]oct-2-en-2-yl 2-methyl-3-methylthio-4-(pentafluoroethyl)benzoate

Base Information

Chemical Name:4-oxobicyclo[3.2.1]oct-2-en-2-yl 2-methyl-3-methylthio-4-(pentafluoroethyl)benzoate
CAS No.:1355556-30-7
Molecular Formula:C₁₉H₁₇F₅O₃S
Molecular Weight:420.4
Hs Code.:

Synonyms:4-oxobicyclo[3.2.1]oct-2-en-2-yl 2-methyl-3-methylthio-4-(pentafluoroethyl)benzoate

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Chemical Property of 4-oxobicyclo[3.2.1]oct-2-en-2-yl 2-methyl-3-methylthio-4-(pentafluoroethyl)benzoate

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Technology Process of 4-oxobicyclo[3.2.1]oct-2-en-2-yl 2-methyl-3-methylthio-4-(pentafluoroethyl)benzoate

There total 8 articles about 4-oxobicyclo[3.2.1]oct-2-en-2-yl 2-methyl-3-methylthio-4-(pentafluoroethyl)benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₁₁H₈ClF₅OS

: 74896-14-3
1,3-bicyclo[3.2.1]octanedione

: 1355556-30-7
4-oxobicyclo[3.2.1]oct-2-en-2-yl 2-methyl-3-methylthio-4-(pentafluoroethyl)benzoate

Guidance literature:: With triethylamine; dmap; In dichloromethane; at 20 ℃; for 16h;

Reference yield:

: 1355157-51-5
3-fluoro-4-(pentafluoroethyl)benzoic acid

: 1355556-30-7
4-oxobicyclo[3.2.1]oct-2-en-2-yl 2-methyl-3-methylthio-4-(pentafluoroethyl)benzoate

Guidance literature:: Multi-step reaction with 6 steps

1.1: N,N,N,N,-tetramethylethylenediamine; n-butyllithium / hexane; tetrahydrofuran / 4 h / -40 - -33 °C

1.2: 17 h / -35 - 20 °C

2.1: sulfuric acid / Reflux

3.1: N,N-dimethyl-formamide / 2 h / 20 °C

4.1: sodium hydroxide; water / methanol / 20 °C

4.2: 0.08 h

5.1: oxalyl dichloride / N,N-dimethyl-formamide / dichloromethane / 0.17 h / Reflux

6.1: triethylamine / dmap / dichloromethane / 16 h / 20 °C

With n-butyllithium; oxalyl dichloride; N,N,N,N,-tetramethylethylenediamine; sulfuric acid; water; triethylamine; sodium hydroxide; dmap; N,N-dimethyl-formamide; In tetrahydrofuran; methanol; hexane; dichloromethane; N,N-dimethyl-formamide;

Reference yield:

: 1355157-53-7
3-fluoro-2-methyl-4-(pentafluoroethyl)benzoic acid

: 1355556-30-7
4-oxobicyclo[3.2.1]oct-2-en-2-yl 2-methyl-3-methylthio-4-(pentafluoroethyl)benzoate

Guidance literature:: Multi-step reaction with 5 steps

1.1: sulfuric acid / Reflux

2.1: N,N-dimethyl-formamide / 2 h / 20 °C

3.1: sodium hydroxide; water / methanol / 20 °C

3.2: 0.08 h

4.1: oxalyl dichloride / N,N-dimethyl-formamide / dichloromethane / 0.17 h / Reflux

5.1: triethylamine / dmap / dichloromethane / 16 h / 20 °C

With oxalyl dichloride; sulfuric acid; water; triethylamine; sodium hydroxide; dmap; N,N-dimethyl-formamide; In methanol; dichloromethane; N,N-dimethyl-formamide;