4-oxobicyclo[3.2.1]oct-2-en-2-yl 2-methyl-3-methylsulfinyl-4-pentafluorethylbenzoate

Base Information

Chemical Name:4-oxobicyclo[3.2.1]oct-2-en-2-yl 2-methyl-3-methylsulfinyl-4-pentafluorethylbenzoate
CAS No.:1355556-32-9
Molecular Formula:C₁₉H₁₇F₅O₄S
Molecular Weight:436.4
Hs Code.:

Synonyms:4-oxobicyclo[3.2.1]oct-2-en-2-yl 2-methyl-3-methylsulfinyl-4-pentafluorethylbenzoate

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Chemical Property of 4-oxobicyclo[3.2.1]oct-2-en-2-yl 2-methyl-3-methylsulfinyl-4-pentafluorethylbenzoate

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Technology Process of 4-oxobicyclo[3.2.1]oct-2-en-2-yl 2-methyl-3-methylsulfinyl-4-pentafluorethylbenzoate

There total 9 articles about 4-oxobicyclo[3.2.1]oct-2-en-2-yl 2-methyl-3-methylsulfinyl-4-pentafluorethylbenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1355556-30-7
4-oxobicyclo[3.2.1]oct-2-en-2-yl 2-methyl-3-methylthio-4-(pentafluoroethyl)benzoate

: 1355556-32-9
4-oxobicyclo[3.2.1]oct-2-en-2-yl 2-methyl-3-methylsulfinyl-4-pentafluorethylbenzoate

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 20 ℃;

Reference yield:

: 1355157-51-5
3-fluoro-4-(pentafluoroethyl)benzoic acid

: 1355556-32-9
4-oxobicyclo[3.2.1]oct-2-en-2-yl 2-methyl-3-methylsulfinyl-4-pentafluorethylbenzoate

Guidance literature:: Multi-step reaction with 7 steps

1.1: N,N,N,N,-tetramethylethylenediamine; n-butyllithium / hexane; tetrahydrofuran / 4 h / -40 - -33 °C

1.2: 17 h / -35 - 20 °C

2.1: sulfuric acid / Reflux

3.1: N,N-dimethyl-formamide / 2 h / 20 °C

4.1: sodium hydroxide; water / methanol / 20 °C

4.2: 0.08 h

5.1: oxalyl dichloride / N,N-dimethyl-formamide / dichloromethane / 0.17 h / Reflux

6.1: triethylamine / dmap / dichloromethane / 16 h / 20 °C

7.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 20 °C

With n-butyllithium; oxalyl dichloride; N,N,N,N,-tetramethylethylenediamine; sulfuric acid; water; triethylamine; 3-chloro-benzenecarboperoxoic acid; sodium hydroxide; dmap; N,N-dimethyl-formamide; In tetrahydrofuran; methanol; hexane; dichloromethane; N,N-dimethyl-formamide;

Reference yield:

: 1355157-53-7
3-fluoro-2-methyl-4-(pentafluoroethyl)benzoic acid

: 1355556-32-9
4-oxobicyclo[3.2.1]oct-2-en-2-yl 2-methyl-3-methylsulfinyl-4-pentafluorethylbenzoate

Guidance literature:: Multi-step reaction with 6 steps

1.1: sulfuric acid / Reflux

2.1: N,N-dimethyl-formamide / 2 h / 20 °C

3.1: sodium hydroxide; water / methanol / 20 °C

3.2: 0.08 h

4.1: oxalyl dichloride / N,N-dimethyl-formamide / dichloromethane / 0.17 h / Reflux

5.1: triethylamine / dmap / dichloromethane / 16 h / 20 °C

6.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 20 °C

With oxalyl dichloride; sulfuric acid; water; triethylamine; 3-chloro-benzenecarboperoxoic acid; sodium hydroxide; dmap; N,N-dimethyl-formamide; In methanol; dichloromethane; N,N-dimethyl-formamide;