anti-Tricyclo[7.1.0.0]decane

Base Information

• Chemical Name: anti-Tricyclo[7.1.0.0]decane
• CAS No.: 81969-73-5
• Molecular Formula: C₁₀H₁₆
• Molecular Weight: 136.237
• Mol file: 81969-73-5.mol

Synonyms:anti-Tricyclo(7.1.0.0)decane;trans-tricyclo[7.1.0.02,4]decane;Tricyclo[7.1.0.02,4]decane;Anti-Tricyclo[7.1.0.02.4]decane;

Chemical Property of anti-Tricyclo[7.1.0.0]decane

Chemical Property:

• Vapor Pressure: 0.881mmHg at 25°C
• Melting Point: 93 - 94 °C
• Boiling Point: 187.1°Cat760mmHg
• Flash Point: 48.9°C
• PSA: 0.00000
• Density: 0.976g/cm³
• LogP: 2.83260

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of anti-Tricyclo[7.1.0.0]decane

There total 3 articles about anti-Tricyclo[7.1.0.0]decane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

1,3-cyclooctadiene (3806-59-5) + 1,1-dibromomethane (74-95-3) → tricyclo<7.1.0.02,4>decane (31083-44-0,81969-73-5)

Guidance literature:

With tetrabutylammomium bromide; In dichloromethane; N,N-dimethyl-formamide; at 40 ℃; electrolysis;

DOI:10.1021/jo00010a015

Reference yield:

diazomethane (186581-53-3,908094-01-9,334-88-3) + 1,3,5,7-cyclooctatetraene (629-20-9) → trans-tricyclo<7.1.0.02,4>decane (81969-73-5)

Guidance literature:

With hydrogen; copper(l) chloride; nickel; In dichloromethane; at -10 - 0 ℃; Yield given; 1.) CH₂Cl₂, -10 - 0 deg C, 2.) 60 deg C, 80 atm, 1 h;

DOI:10.1007/BF00952847

Reference yield:

trans-7,7,10,10-tetrachlorotricyclo<7.1.0.06,8>decane (58189-51-8,63180-22-3,126721-99-1) → trans-tricyclo<7.1.0.02,4>decane (81969-73-5)

Guidance literature:

With lithium; tert-butyl alcohol; In tetrahydrofuran; for 12h; Heating;

DOI:10.1021/jo00137a011

upstream raw materials:

diazomethane

1,3,5,7-cyclooctatetraene

trans-7,7,10,10-tetrachlorotricyclo<7.1.0.0^6,8>decane

1,3-cyclooctadiene