Ethanone, 1-(1R,2S,4R)-bicyclo[2.2.1]hept-5-en-2-yl- (9CI)

Base Information

Chemical Name:Ethanone, 1-(1R,2S,4R)-bicyclo[2.2.1]hept-5-en-2-yl- (9CI)
CAS No.:159699-92-0
Molecular Formula:C9H12 O
Molecular Weight:136.194
Hs Code.:
Mol file:159699-92-0.mol

Synonyms:Ethanone,1-bicyclo[2.2.1]hept-5-en-2-yl-, (1R-exo)-; (1R-exo)-2-Acetyl-5-Norbornene

Suppliers and Price of Ethanone, 1-(1R,2S,4R)-bicyclo[2.2.1]hept-5-en-2-yl- (9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of Ethanone, 1-(1R,2S,4R)-bicyclo[2.2.1]hept-5-en-2-yl- (9CI)

Chemical Property:

PSA：17.07000
LogP:1.78760

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Ethanone, 1-(1R,2S,4R)-bicyclo[2.2.1]hept-5-en-2-yl- (9CI)

There total 3 articles about Ethanone, 1-(1R,2S,4R)-bicyclo[2.2.1]hept-5-en-2-yl- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 0.3%

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 78-94-4,25038-87-3
methyl vinyl ketone

: 77-73-6,933-60-8,1755-01-7,13257-74-4,25850-35-5,57429-84-2,109428-68-4,25038-78-2
dicyclopentadiene

: 159699-92-0
(2S)-1-bicyclo[2.2.1]hept-5-en-2-yl-ethanone

: 107740-92-1
endo-2-acetyl-bicyclo[2.2.1]hept-5-ene

Guidance literature:: at 20 - 67 ℃; Product distribution / selectivity;

Reference yield:

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 78-94-4,25038-87-3
methyl vinyl ketone

: 5063-03-6
2-acetyl-5-norbornene

: 159651-24-8
C₉H₁₂O

: 159699-92-0
(2S)-1-bicyclo[2.2.1]hept-5-en-2-yl-ethanone

Guidance literature:: With [Ru(η5-C8H7)((S,S)-BIPHOP-F)(acetone)][SbF6]; lithium diisopropyl amide; In dichloromethane; at -20 ℃; for 48h; Overall yield = 76 %; Overall yield = 68.4 mg; Molecular sieve; Schlenk technique; Inert atmosphere;
DOI:10.1002/hlca.201600139

Reference yield:

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 292638-85-8,9003-21-8,96-33-3
acrylic acid methyl ester

: 159699-92-0
(2S)-1-bicyclo[2.2.1]hept-5-en-2-yl-ethanone

: 824-60-2,824-61-3,5063-03-6,65166-67-8,107740-92-1,128441-68-9,58001-95-9
bicyclo[2.2.1]hept-5-ene-2-carboxylic acid methyl ester

: 107740-92-1
endo-2-acetyl-bicyclo[2.2.1]hept-5-ene

Guidance literature:: With (4RS,11bS)-4-(2-((ethylthio)methyl)phenyl)-4,5-dihydro-3H-dinaphtho[2,1-c:1′,2′-e]silepinylium tetrakis(pentafluorophenyl)borate; In 1,2-dichloro-benzene; at 20 ℃; for 1h; Overall yield = 72 %; Overall yield = 55 mg; stereoselective reaction; Glovebox; Inert atmosphere; Schlenk technique;
DOI:10.1021/acs.organomet.5b00351