(1E,3E,5R,7R,8S)-9-(3,4-dimethoxybenzyloxy)-1-iodo-7-methoxy-8-methylnona-1,3-dien-5-ol

Base Information

Chemical Name:(1E,3E,5R,7R,8S)-9-(3,4-dimethoxybenzyloxy)-1-iodo-7-methoxy-8-methylnona-1,3-dien-5-ol
CAS No.:1256633-75-6
Molecular Formula:C₂₀H₂₉IO₅
Molecular Weight:476.352
Hs Code.:

Synonyms:(1E,3E,5R,7R,8S)-9-(3,4-dimethoxybenzyloxy)-1-iodo-7-methoxy-8-methylnona-1,3-dien-5-ol

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Chemical Property of (1E,3E,5R,7R,8S)-9-(3,4-dimethoxybenzyloxy)-1-iodo-7-methoxy-8-methylnona-1,3-dien-5-ol

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Technology Process of (1E,3E,5R,7R,8S)-9-(3,4-dimethoxybenzyloxy)-1-iodo-7-methoxy-8-methylnona-1,3-dien-5-ol

There total 5 articles about (1E,3E,5R,7R,8S)-9-(3,4-dimethoxybenzyloxy)-1-iodo-7-methoxy-8-methylnona-1,3-dien-5-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 1256633-74-5
(1E,3E,5R,7R,8S)-9-(3,4-dimethoxybenzyloxy)-1-iodo-7-methoxy-8-methylnona-1,3-dien-5-yl propionate

: 1256633-75-6
(1E,3E,5R,7R,8S)-9-(3,4-dimethoxybenzyloxy)-1-iodo-7-methoxy-8-methylnona-1,3-dien-5-ol

Guidance literature:: With methanol; potassium carbonate; at 20 ℃; for 16h; Inert atmosphere;
DOI:10.1021/ol102425n

Reference yield:

: 1256633-59-6
(2S,5R,6E,8E)-1-(3,4-dimethoxybenzyloxy)-5-hydroxy-9-iodo-2-methylnona-6,8-dien-3-one

: 1256633-75-6
(1E,3E,5R,7R,8S)-9-(3,4-dimethoxybenzyloxy)-1-iodo-7-methoxy-8-methylnona-1,3-dien-5-ol

Guidance literature:: Multi-step reaction with 3 steps

1: samarium diiodide / tetrahydrofuran / 0.75 h / -20 °C / Inert atmosphere

2: dichloromethane / 1 h / 20 °C / Inert atmosphere

3: methanol; potassium carbonate / 16 h / 20 °C / Inert atmosphere

With methanol; samarium diiodide; potassium carbonate; In tetrahydrofuran; dichloromethane; 1: Evans-Tishchenko reduction;
DOI:10.1021/ol102425n

Reference yield:

: 1256633-60-9
C₂₂H₃₁IO₆

: 1256633-75-6
(1E,3E,5R,7R,8S)-9-(3,4-dimethoxybenzyloxy)-1-iodo-7-methoxy-8-methylnona-1,3-dien-5-ol

Guidance literature:: Multi-step reaction with 2 steps

1: dichloromethane / 1 h / 20 °C / Inert atmosphere

2: methanol; potassium carbonate / 16 h / 20 °C / Inert atmosphere

With methanol; potassium carbonate; In dichloromethane;
DOI:10.1021/ol102425n