1-[4-(4-dimethylaminophenylazo)-3-(3,5-bis(tert-butyldimethylsilyloxy)phenyl)phenyl]-2,2,2-trifluoroethanone

Base Information

• Chemical Name: 1-[4-(4-dimethylaminophenylazo)-3-(3,5-bis(tert-butyldimethylsilyloxy)phenyl)phenyl]-2,2,2-trifluoroethanone
• CAS No.: 514225-87-7
• Molecular Formula: C₃₄H₄₆F₃N₃O₃Si₂
• Molecular Weight: 657.924
• Mol file: 514225-87-7.mol

Synonyms:1-[4-(4-dimethylaminophenylazo)-3-(3,5-bis(tert-butyldimethylsilyloxy)phenyl)phenyl]-2,2,2-trifluoroethanone

Chemical Property of 1-[4-(4-dimethylaminophenylazo)-3-(3,5-bis(tert-butyldimethylsilyloxy)phenyl)phenyl]-2,2,2-trifluoroethanone

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of 1-[4-(4-dimethylaminophenylazo)-3-(3,5-bis(tert-butyldimethylsilyloxy)phenyl)phenyl]-2,2,2-trifluoroethanone

There total 1 articles about 1-[4-(4-dimethylaminophenylazo)-3-(3,5-bis(tert-butyldimethylsilyloxy)phenyl)phenyl]-2,2,2-trifluoroethanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

1-[4-(4-dimethylaminophenylazo)-3-iodo-phenyl]-2,2,2-trifluoroethanone (514225-86-6) + 2,4,6-tris-[3,5-bis-(tert-butyl-dimethyl-silanyloxy)-phenyl]-cyclotriboroxane → 1-[4-(4-dimethylaminophenylazo)-3-(3,5-bis(tert-butyldimethylsilyloxy)phenyl)phenyl]-2,2,2-trifluoroethanone (514225-87-7)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate; In ethanol; benzene; at 50 - 55 ℃; for 5h;

DOI:10.1016/j.tet.2004.08.100

Reference yield: 54.0%

1-[4-(4-dimethylaminophenylazo)-3-(3,5-bis(tert-butyldimethylsilyloxy)phenyl)phenyl]-2,2,2-trifluoroethanone (514225-87-7) + C73H75BrO14 → 1-[3'-{3,5-bis-[3,5-bis-(3,5-bis-allyloxy-benzyloxy)-benzyloxy]-benzyloxy}-6-(4-dimethylamino-phenylazo)-5'-hydroxy-biphenyl-3-yl]-2,2,2-trifluoro-ethanone + 1-[4-(4-dimethylaminophenylazo)-3-[{3,5-bis[3,5-bis(3,5-bis(2-propen-1-oxy)benzyloxy)benzyloxy]benzyloxy}phenyl]]-2,2,2-trifluoroethanone

Guidance literature:

With potassium fluoride; 18-crown-6 ether; In tetrahydrofuran; at 60 ℃; for 40h;

DOI:10.1016/j.tet.2004.08.100

Reference yield: 44.0%

C81H91BrO14 + 1-[4-(4-dimethylaminophenylazo)-3-(3,5-bis(tert-butyldimethylsilyloxy)phenyl)phenyl]-2,2,2-trifluoroethanone (514225-87-7) → 1-[4-(4-dimethylaminophenylazo)-3-[{3,5-bis[3,5-bis(3,5-bis(3-buten-1-oxy)benzyloxy)benzyloxy]benzyloxy}phenyl]]-2,2,2-trifluoroethanone

Guidance literature:

With potassium fluoride; 18-crown-6 ether; In tetrahydrofuran; at 60 ℃; for 29h;

DOI:10.1016/j.tet.2004.08.100

upstream raw materials:

1-[4-(4-dimethylaminophenylazo)-3-iodo-phenyl]-2,2,2-trifluoroethanone