methyl (1S)-(+)-2,2-dimethyl-6-methylene-1-cyclohexanecarboxylate

Base Information

• Chemical Name: methyl (1S)-(+)-2,2-dimethyl-6-methylene-1-cyclohexanecarboxylate
• CAS No.: 166239-08-3
• Molecular Formula: C₁₁H₁₈O₂
• Molecular Weight: 182.263
• Mol file: 166239-08-3.mol

Synonyms:methyl (1S)-(+)-2,2-dimethyl-6-methylene-1-cyclohexanecarboxylate

Chemical Property of methyl (1S)-(+)-2,2-dimethyl-6-methylene-1-cyclohexanecarboxylate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of methyl (1S)-(+)-2,2-dimethyl-6-methylene-1-cyclohexanecarboxylate

There total 2 articles about methyl (1S)-(+)-2,2-dimethyl-6-methylene-1-cyclohexanecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.4%

diazomethane (186581-53-3,908094-01-9,334-88-3) + (1S)-(+)-2,2-dimethyl-6-methylene-1-cyclohexanecarboxylic acid (166022-22-6) → methyl (1S)-(+)-2,2-dimethyl-6-methylene-1-cyclohexanecarboxylate (166239-08-3)

Guidance literature:

DOI:10.1016/S0040-4020(97)00103-8

Reference yield:

(1S)-(+)-2,2-dimethyl-6-methylene-1-cyclohexanecarboxylic acid (166022-22-6) + methyl iodide (74-88-4) → methyl (1S)-(+)-2,2-dimethyl-6-methylene-1-cyclohexanecarboxylate (166239-08-3)

Guidance literature:

With potassium carbonate; In acetone; for 1.5h; Heating;

DOI:10.1002/hlca.19950780303

Reference yield: 90.6%

methyl (1S)-(+)-2,2-dimethyl-6-methylene-1-cyclohexanecarboxylate (166239-08-3) → (S)-(+)-(2',2'-dimethyl-6'-methylene-1'-cyclohexyl)methanol (166022-29-3)

Guidance literature:

With lithium aluminium tetrahydride;

DOI:10.1016/S0040-4020(97)00103-8

upstream raw materials:

(1S)-(+)-2,2-dimethyl-6-methylene-1-cyclohexanecarboxylic acid

methyl iodide

diazomethane

Downstream raw materials:

(S)-(+)-1-(2',2'-dimethyl-6'-methylene-1'-cyclohexyl)but-3-en-1-one

(S)-(+)-(2',2'-dimethyl-6'-methylene-1'-cyclohexyl)methanol

(1R,4aα)-1-[(E)-6-[(S)-2,2-dimethyl-6-methylenecyclohexyl]-4-methyl-3-hexenyl]decahydro-2,5,5,8aβ-tetramethylnaphthalene-2α-ol

(S)-2-Chloromethyl-1,1-dimethyl-3-methylene-cyclohexane