Technology Process of [Pd(1,2-bis(diphenylphosphino)ethane)2](PF6)2
There total 8 articles about [Pd(1,2-bis(diphenylphosphino)ethane)2](PF6)2 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
In
dichloromethane;
byproducts: AgCl; (N2); using Schlenk techniques; addn. of AgPF6 (2 equiv.) to stirred soln. of PdCl2(1,2-bis(diphenylphosphino)ethane) (1 equiv.) and dppe (1 equiv.) in CH2Cl2 at room temp.; stirring for 30 min; passing through a column of Celite, concn. under vac., addn. of diethyl ether, pptn., elem. anal.;
DOI:10.1021/om010727b
- Guidance literature:
-
With
CO; C2H4;
In
dichloromethane-d2;
(N2); using Schlenk techniques; charging of NMR tube with a soln. of PdC29H30F6NP3 in CD2Cl2 at room temp.; treatment with CO/ethene (1:1) mixt.at 40 bar; heating at 70°C for 15 min; not isolated, detected by NMR;
DOI:10.1021/om010727b
- Guidance literature:
-
With
CO; C2H4;
In
dichloromethane-d2; water;
(N2); using Schlenk techniques; charging of NMR tube with a soln. of PdC29H30F6NP3 in CD2Cl2 at room temp. in the presence of water; heating with CO/ethene (1:1) mixt. under 40 bar at 50°C for 30 min; heating at 70°C for 1 h; not isolated, detected by NMR;
DOI:10.1021/om010727b
