4-((2S,3S,4R,5R,6R)-3,4,5-Tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-ylmethyl)-phenol

Base Information

Chemical Name:4-((2S,3S,4R,5R,6R)-3,4,5-Tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-ylmethyl)-phenol
CAS No.:201148-54-1
Molecular Formula:C₄₁H₄₂O₆
Molecular Weight:630.781
Hs Code.:

Synonyms:4-((2S,3S,4R,5R,6R)-3,4,5-Tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-ylmethyl)-phenol

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Chemical Property of 4-((2S,3S,4R,5R,6R)-3,4,5-Tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-ylmethyl)-phenol

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Technology Process of 4-((2S,3S,4R,5R,6R)-3,4,5-Tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-ylmethyl)-phenol

There total 3 articles about 4-((2S,3S,4R,5R,6R)-3,4,5-Tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-ylmethyl)-phenol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 13096-62-3
(3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-one

: 201148-54-1
4-((2S,3S,4R,5R,6R)-3,4,5-Tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-ylmethyl)-phenol

Guidance literature:: Multi-step reaction with 2 steps

1: Cp₂Ti(Me)2 / toluene / Heating

2: 1.) 9-BBN-H; 2.) PdCl₂(dppf), aq. K₃PO₄ / 1.) THF, reflux, 7 h; 2.) THF, DMF, rt, 18 h

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium phosphate; 9-borabicyclo[3.3.1]nonane dimer; dimethyltitanocene; In toluene;
DOI:10.1055/s-0030-1260180

Reference yield:

: 4291-69-4,6386-24-9,6564-72-3,59531-24-7,69257-52-9,78184-89-1,78609-16-2,78609-17-3,78609-18-4,96553-53-6,104111-61-7,131347-08-5,4132-28-9
2,3,4,6-Tetra-O-benzyl-D-glucopyranose

: 201148-54-1
4-((2S,3S,4R,5R,6R)-3,4,5-Tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-ylmethyl)-phenol

Guidance literature:: Multi-step reaction with 3 steps

1: PCC, MS / CH₂Cl₂

2: Cp₂Ti(Me)2 / toluene / Heating

3: 1.) 9-BBN-H; 2.) PdCl₂(dppf), aq. K₃PO₄ / 1.) THF, reflux, 7 h; 2.) THF, DMF, rt, 18 h

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium phosphate; 9-borabicyclo[3.3.1]nonane dimer; dimethyltitanocene; pyridinium chlorochromate; In dichloromethane; toluene;
DOI:10.1055/s-0030-1260180

Reference yield:

: 540-38-5
p-Iodophenol

: 133697-34-4,97321-70-5
2,6-anhydro-3,4,5,7-tetra-O-benzyl-1-deoxy-D-gluco-hept-1-enitol

: 201148-54-1
4-((2S,3S,4R,5R,6R)-3,4,5-Tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-ylmethyl)-phenol

Guidance literature:: With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium phosphate; 9-borabicyclo[3.3.1]nonane dimer; Yield given. Multistep reaction; 1.) THF, reflux, 7 h; 2.) THF, DMF, rt, 18 h;
DOI:10.1055/s-0030-1260180