(S)-3-(4-nitro-phenyl)-3-(1,1,3,3-tetraoxo-2,3-dihydro-1H-1λ(6),3λ(6)-benzo[1,3]dithiol-2-yl)-propionaldehyde

Base Information

Chemical Name:(S)-3-(4-nitro-phenyl)-3-(1,1,3,3-tetraoxo-2,3-dihydro-1H-1λ(6),3λ(6)-benzo[1,3]dithiol-2-yl)-propionaldehyde
CAS No.:1222468-64-5
Molecular Formula:C₁₆H₁₃NO₇S₂
Molecular Weight:395.414
Hs Code.:

Synonyms:(S)-3-(4-nitro-phenyl)-3-(1,1,3,3-tetraoxo-2,3-dihydro-1H-1λ(6),3λ(6)-benzo[1,3]dithiol-2-yl)-propionaldehyde

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Chemical Property of (S)-3-(4-nitro-phenyl)-3-(1,1,3,3-tetraoxo-2,3-dihydro-1H-1λ(6),3λ(6)-benzo[1,3]dithiol-2-yl)-propionaldehyde

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Technology Process of (S)-3-(4-nitro-phenyl)-3-(1,1,3,3-tetraoxo-2,3-dihydro-1H-1λ(6),3λ(6)-benzo[1,3]dithiol-2-yl)-propionaldehyde

There total 1 articles about (S)-3-(4-nitro-phenyl)-3-(1,1,3,3-tetraoxo-2,3-dihydro-1H-1λ(6),3λ(6)-benzo[1,3]dithiol-2-yl)-propionaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 1734-79-8
3-(4-nitrophenyl)-2-propenal

: 112520-09-9
2H-benzo[d][1,3]dithiole 1,1,3,3-tetraoxide

: 1222468-64-5
(S)-3-(4-nitro-phenyl)-3-(1,1,3,3-tetraoxo-2,3-dihydro-1H-1λ(6),3λ(6)-benzo[1,3]dithiol-2-yl)-propionaldehyde

Guidance literature:: With (S)-2-(((tert-butyldimethylsilyl)oxy)diphenylmethyl)pyrrolidine; benzoic acid; In toluene; at 20 ℃; for 43h; enantioselective reaction;
DOI:10.1016/j.tetlet.2010.01.102

Reference yield:

: 1222468-64-5
(S)-3-(4-nitro-phenyl)-3-(1,1,3,3-tetraoxo-2,3-dihydro-1H-1λ(6),3λ(6)-benzo[1,3]dithiol-2-yl)-propionaldehyde

: C₁₆H₁₅NO₇S₂

Guidance literature:: With sodium tetrahydroborate; In methanol; at 20 ℃; for 0.333333h; enantioselective reaction;
DOI:10.1016/j.tetlet.2010.01.102

Reference yield:

: 1222468-64-5
(S)-3-(4-nitro-phenyl)-3-(1,1,3,3-tetraoxo-2,3-dihydro-1H-1λ(6),3λ(6)-benzo[1,3]dithiol-2-yl)-propionaldehyde

: 149-73-5
trimethyl orthoformate

: 1203466-62-9
(S)-3-[(benzo[1,3]dithiole-1,1,3,3-tetraoxide)-2-yl]-3-(4-nitrophenyl)propanaldehyde dimethyl acetal

Guidance literature:: With indium(III) triflate; In dichloromethane; at 20 ℃; for 0.5h; optical yield given as %ee; Inert atmosphere;
DOI:10.1002/chem.200902094