ferrocenium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

Base Information

• Chemical Name: ferrocenium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate
• CAS No.: 156301-37-0
• Molecular Formula: C₁₀H₁₀Fe*C₃₂H₁₂BF₂₄
• Molecular Weight: 1049.26

Synonyms:ferrocenium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

Chemical Property of ferrocenium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

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Technology Process of ferrocenium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

There total 5 articles about ferrocenium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

ferrocenium(III) tetrafluoroborate (1282-37-7) + sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate (79060-88-1) → ferrocenium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (156301-37-0)

Guidance literature:

In dichloromethane; (N2); refluxed for 30 min; evapd. (vac.), extd. (Et2O), concd. (vac.), pptd. (pentane), filtered, washed (pentane), dried (vac.), recrystd. (pentane diffusion into concd.CH2Cl2 soln. for 24 h), washed (pentane), dried (vac.); elem. anal.;

DOI:10.1016/S0022-328X(00)00044-9

Reference yield: 83.0%

Fe(C5H5)2(1+)*HSO4(1-)=[Fe(C5H5)2]HSO4 (37298-35-4) + sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate (79060-88-1) → ferrocenium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (156301-37-0)

Guidance literature:

In water; in air; treatment of Fe-complex/water (generated from Cp2Fe and 96% H2SO4) with an aq. soln. of the borate; elem. anal.;

Reference yield: 82.0%

tetrakis[3,5-bis(trifluoromethyl)phenyl]boric acid bis(diethyl ether) complex + ferrocene (102-54-5,55404-68-7) → ferrocenium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (156301-37-0)

Guidance literature:

With p-benzoquinone; In dichloromethane; (N2); Fe complex soln. in CH2Cl2 added slowly to CH2Cl2 contg. p-benzoquinone and B complex, stirred at room temp. for 1 h; solvent removed (vac.) and concd., pptd. (pentane), filtered, washed (pentane), dried (vac.);

DOI:10.1016/S0022-328X(00)00044-9

upstream raw materials:

ferrocene

potassium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

ferrocenium(III) tetrafluoroborate

sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate

Downstream raw materials:

Nb[C₆H₃(CH₃)3]2⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)=[Nb(C₆H₃(CH₃)3)2][B(C₆H₃(CF₃)2)4]

[N(CH₂CH₂NC₆F₅)3W(CNBu-t)]B(C₆H₃(CF₃)2-3,5)4

[N(CH₂CH₂NC₆F₅)3Mo(CNBu-t)]B(C₆H₃(CF₃)2-3,5)4

[N(CH₂CH₂NC₆F₅)3W(CNC₆H₃Me₂-2,6)]B(C₆H₃(CF₃)2-3,5)4

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