(1S,2S)-1-benzyloxy-3-(2-tert-butyldimethylsilanyl-1,3-dithian-2-yl)-1-((1S)-oxiranyl)propan-2-ol

Base Information

Chemical Name:(1S,2S)-1-benzyloxy-3-(2-tert-butyldimethylsilanyl-1,3-dithian-2-yl)-1-((1S)-oxiranyl)propan-2-ol
CAS No.:870294-72-7
Molecular Formula:C₂₂H₃₆O₃S₂Si
Molecular Weight:440.744
Hs Code.:

Synonyms:(1S,2S)-1-benzyloxy-3-(2-tert-butyldimethylsilanyl-1,3-dithian-2-yl)-1-((1S)-oxiranyl)propan-2-ol

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Chemical Property of (1S,2S)-1-benzyloxy-3-(2-tert-butyldimethylsilanyl-1,3-dithian-2-yl)-1-((1S)-oxiranyl)propan-2-ol

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Technology Process of (1S,2S)-1-benzyloxy-3-(2-tert-butyldimethylsilanyl-1,3-dithian-2-yl)-1-((1S)-oxiranyl)propan-2-ol

There total 2 articles about (1S,2S)-1-benzyloxy-3-(2-tert-butyldimethylsilanyl-1,3-dithian-2-yl)-1-((1S)-oxiranyl)propan-2-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

: 118227-49-9,136741-00-9,150198-78-0
(2S,4S)-1,2:4,5-dianhydro-3-(benzyl)arabitol

: 95452-06-5
tert-butyl(1,3-dithian-2-yl)dimethylsilane

: 870294-72-7
(1S,2S)-1-benzyloxy-3-(2-tert-butyldimethylsilanyl-1,3-dithian-2-yl)-1-((1S)-oxiranyl)propan-2-ol

: (1R,2S)-1-benzyloxy-3-(2-tert-butyldimethylsilanyl-1,3-dithian-2-yl)-1-((1S)-oxiranyl)propan-2-ol

: (2S,4S)-3-benzyloxy-1,5-bis(2-(tert-butyldimethylsilyl)-1,3-dithian-2-yl)pentane-2,4-diol

Guidance literature:: tert-butyl(1,3-dithian-2-yl)dimethylsilane; With tert.-butyl lithium; In diethyl ether; pentane; at -78 ℃;

(2S,4S)-1,2:4,5-dianhydro-3-(benzyl)arabitol; In diethyl ether; pentane; at -78 - -20 ℃; for 2h;
DOI:10.1021/ol052009h

Reference yield:

: 118227-49-9,136741-00-9,150198-78-0
(2S,4S)-1,2:4,5-dianhydro-3-(benzyl)arabitol

: 95452-06-5
tert-butyl(1,3-dithian-2-yl)dimethylsilane

: 870294-72-7
(1S,2S)-1-benzyloxy-3-(2-tert-butyldimethylsilanyl-1,3-dithian-2-yl)-1-((1S)-oxiranyl)propan-2-ol

: (1R,2S)-1-benzyloxy-3-(2-tert-butyldimethylsilanyl-1,3-dithian-2-yl)-1-((1S)-oxiranyl)propan-2-ol

Guidance literature:: tert-butyl(1,3-dithian-2-yl)dimethylsilane; With tert.-butyl lithium; lithium perchlorate; In diethyl ether; pentane; at -78 - -30 ℃; for 1.5h; Inert atmosphere;

(2S,4S)-1,2:4,5-dianhydro-3-(benzyl)arabitol; In diethyl ether; pentane; at -78 ℃; for 4h; Inert atmosphere;
DOI:10.1021/jo801848h

Reference yield: 26.0%

: 870294-72-7
(1S,2S)-1-benzyloxy-3-(2-tert-butyldimethylsilanyl-1,3-dithian-2-yl)-1-((1S)-oxiranyl)propan-2-ol

: 2-[(3R)-benzyloxy-(2S)-tert-butyldimethylsilyloxy-3-((1S)-oxiranyl)propyl]-1,3-dithiane

: 870294-67-0
(2R,3R,4S)-[3-benzyloxy-4-(tert-butyldimethylsilyloxy)-2-hydroxymethyl]cyclopentan-1-one-1,3-propanedithioketal

Guidance literature:: With tert.-butyl lithium; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; pentane; at -30 ℃; for 1h; Inert atmosphere; Molecular sieve;
DOI:10.1021/jo801848h