tris(2,4-dimethoxyphenyl)bismuth dichloride

Base Information

• Chemical Name: tris(2,4-dimethoxyphenyl)bismuth dichloride
• CAS No.: 895154-83-3
• Molecular Formula: C₂₄H₂₇BiCl₂O₆
• Molecular Weight: 691.361
• Mol file: 895154-83-3.mol

Synonyms:tris(2,4-dimethoxyphenyl)bismuth dichloride

Chemical Property of tris(2,4-dimethoxyphenyl)bismuth dichloride

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of tris(2,4-dimethoxyphenyl)bismuth dichloride

There total 1 articles about tris(2,4-dimethoxyphenyl)bismuth dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

sulfuryl dichloride (7791-25-5) + tris(2,4-dimethoxyphenyl)bismuthane (161259-72-9) → tris(2,4-dimethoxyphenyl)bismuth dichloride (895154-83-3)

Guidance literature:

In dichloromethane; cold soln. (-78°C) of SO2Cl2 in CH2Cl2 was added to stirred soln.of Bi compd. in CH2Cl2 at -78°C under Ar; warmed to ambient temp .; volatiles distd. (vac.); recrystd. (CH2Cl2/Et2O); elem. anal.;

DOI:10.1016/j.jorganchem.2006.01.022

Reference yield: 69.0%

tris(2,4-dimethoxyphenyl)bismuth dichloride (895154-83-3) + β-naphthol (135-19-3) → 1-(2,4-dimethoxyphenyl)naphthalen-2-ol

Guidance literature:

With N,N,N',N'-tetramethylguanidine; In tetrahydrofuran; at 20 ℃; for 15h;

DOI:10.1016/j.jorganchem.2006.01.022

Reference yield: 43.0%

tris(2,4-dimethoxyphenyl)bismuth dichloride (895154-83-3) + ethyl 2-oxocyclohexane carboxylate (1655-07-8) → ethyl 1-(2',4'-dimethoxyphenyl)-2-oxocyclohexanecarboxylate

Guidance literature:

With N,N,N',N'-tetramethylguanidine; In tetrahydrofuran; at 20 ℃; for 16h;

DOI:10.1016/j.jorganchem.2006.01.022

upstream raw materials:

sulfuryl dichloride

tris(2,4-dimethoxyphenyl)bismuthane

Downstream raw materials:

3-(2',4'-dimethoxyphenyl)-4-hydroxy-5,7-dimethoxy-2H-1-benzopyrane-2-one