HFe3(μ2-COCH3)(carbonyl)10

Base Information

Chemical Name:HFe3(μ2-COCH3)(carbonyl)10
CAS No.:55992-19-3
Molecular Formula:C₁₂H₄Fe₃O₁₁
Molecular Weight:491.698
Hs Code.:

Synonyms:HFe3(μ2-COCH3)(carbonyl)10

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Chemical Property of HFe3(μ2-COCH3)(carbonyl)10

Chemical Property:

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MSDS Files:: SDS file from LookChem

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Technology Process of HFe3(μ2-COCH3)(carbonyl)10

There total 2 articles about HFe3(μ2-COCH3)(carbonyl)10 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 34.0%

: 17685-52-8
triiron dodecarbonyl

: 420-37-1
trimethoxonium tetrafluoroborate

: 13463-40-6,37220-42-1
iron pentacarbonyl

: 55992-19-3
HFe3(μ2-COCH3)(carbonyl)10

: 103751-58-2
Fe3(μ3-vinylidene)(carbonyl)10

: 112220-73-2
Fe3(μ3-methylidenemethylether)2(carbonyl)9

: 75983-14-1
HFe₄(carbonyl)12(COMe)

Guidance literature:: With t-buthyl lithium; In diethyl ether; Addn. of t-BuLi (over 10 min, -60°C) to Fe3(CO)12 in Et2O (Ar), stirring (3 h, temp. allowed to rise to -30°C), removing cooling bath, stirring (2 h), evapn., addn. of H2O/n-hexane, treating with Me3OBF4 with stirring; further products.; Organic layer is separated, aq. layer is extd. (n-hexane), organic soln. is dried (Na2SO4, 1 h) and concd., chromy. (silica gel, n-hexane).;

Reference yield: 19.0%

: 15321-51-4
diiron nonacarbonyl

: 420-37-1
trimethoxonium tetrafluoroborate

: 591-51-5
phenyllithium

: 13463-40-6,37220-42-1
iron pentacarbonyl

: 55992-19-3
HFe3(μ2-COCH3)(carbonyl)10

: 103751-58-2
Fe3(μ3-vinylidene)(carbonyl)10

: 112220-73-2
Fe3(μ3-methylidenemethylether)2(carbonyl)9

: 75983-14-1
HFe₄(carbonyl)12(COMe)

Guidance literature:: In diethyl ether; Dropwise addn. of PhLi to Fe2(CO)9 (Et2O, -5°C, Ar, over 1 h), stirring (2 h), evapn., addn. of H2O and n-hexane, treating with Me3OBF4 with stirring.; Organic layer is separated, aq. layer is extd. (n-hexane), organic soln. is dried (Na2SO4, 1 h) and concd., chromy. (silica gel, n-hexane).;

Reference yield: 62.0%

: methyl(triphenylphosphine)gold(I)

: 55992-19-3
HFe3(μ2-COCH3)(carbonyl)10

: AuFe₃(COCH₃)(CO)10P(C₆H₅)3

Guidance literature:: In diethyl ether; soln. of Fe complex treated with AuMe(PPh3), stirred at room temp. overnight; concd. in vac., chromd. (CH2Cl2-light petroleum), solvent evapd., recrystd. from light petroleum; elem anal.;