1-Bromocyclopropyl phenyl sulfide

Base Information

• Chemical Name: 1-Bromocyclopropyl phenyl sulfide
• CAS No.: 78709-01-0
• Molecular Formula: C₉H₉BrS
• Molecular Weight: 229.14
• Mol file: 78709-01-0.mol

Synonyms:1-Bromocyclopropyl phenyl sulfide

Chemical Property of 1-Bromocyclopropyl phenyl sulfide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-Bromocyclopropyl phenyl sulfide

There total 4 articles about 1-Bromocyclopropyl phenyl sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

1-(phenylthio)cyclopropanol (79306-18-6) → 1-Bromocyclopropyl phenyl sulfide (78709-01-0)

Guidance literature:

With hydrogen bromide; In liquid sulphur dioxide; at -30 ℃; for 0.25h;

Reference yield: 30.0%

1-(phenylthio)cyclopropanol (79306-18-6) → S-phenylthiopropionate (18245-72-2) + 1-Bromocyclopropyl phenyl sulfide (78709-01-0)

Guidance literature:

With hydrogen bromide; In dichloromethane; for 5h; Ambient temperature;

Reference yield:

benzyl bromide (100-39-0) + 1-lithio-1-(phenylthio)-cyclopropane (41596-88-7) → 1-Bromocyclopropyl phenyl sulfide (78709-01-0) + 1,1'-(1,2-ethanediyl)bisbenzene (103-29-7)

Guidance literature:

In tetrahydrofuran; 1.) -78 deg C, 3 h, 2.) 20 deg C, overnight;

DOI:10.1016/S0040-4039(00)87347-5

upstream raw materials:

benzyl bromide

1-lithio-1-(phenylthio)-cyclopropane

1-(phenylthio)cyclopropanol

thiophenol

Downstream raw materials:

cyclopropylphenylsulfide

1-methoxy-1-(phenylthio)cyclopropane

1-(methylthio)-1-(phenylthio)cyclopropane