Technology Process of 6-azido-3,7-dimethyloctyl benzoate
There total 2 articles about 6-azido-3,7-dimethyloctyl benzoate which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
3,7-dimethyloct-6-en-1-yl benzoate;
With
N,N-dimethyl acetamide; benzo[1,3,2]dioxaborole;
In
dichloromethane;
at 0 ℃;
for 5h;
Reflux;
Inert atmosphere;
With
phenylsulfonyl azide; trans-di-O-tert-butyl hyponitrite;
In
N,N-dimethyl-formamide;
at 80 ℃;
regioselective reaction;
Inert atmosphere;
DOI:10.1021/ja2054989
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: pyridine / 3 h / 20 °C / Inert atmosphere
2.1: N,N-dimethyl acetamide; benzo[1,3,2]dioxaborole / dichloromethane / 5 h / 0 °C / Reflux; Inert atmosphere
2.2: 80 °C / Inert atmosphere
With
pyridine; N,N-dimethyl acetamide; benzo[1,3,2]dioxaborole;
In
dichloromethane;
DOI:10.1021/ja2054989
