2-(1,4,7,10tetraoxa-cyclododec-2-ylmethoxymethyl)-benzoic acid tert-butyl ester

Base Information

Chemical Name:2-(1,4,7,10tetraoxa-cyclododec-2-ylmethoxymethyl)-benzoic acid tert-butyl ester
CAS No.:864851-88-7
Molecular Formula:C₂₁H₃₂O₇
Molecular Weight:396.481
Hs Code.:

2-(1,4,7,10tetraoxa-cyclododec-2-ylmethoxymethyl)-benzoic acid <i>tert</i>-butyl ester

Synonyms:2-(1,4,7,10tetraoxa-cyclododec-2-ylmethoxymethyl)-benzoic acid tert-butyl ester

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Chemical Property of 2-(1,4,7,10tetraoxa-cyclododec-2-ylmethoxymethyl)-benzoic acid tert-butyl ester

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Technology Process of 2-(1,4,7,10tetraoxa-cyclododec-2-ylmethoxymethyl)-benzoic acid tert-butyl ester

There total 4 articles about 2-(1,4,7,10tetraoxa-cyclododec-2-ylmethoxymethyl)-benzoic acid tert-butyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 75507-26-5
2-(hydroxymethyl)-12-crown-4

: 105340-30-5
2-(bromomethyl)benzoic acid t-butyl ester

: 864851-88-7
2-(1,4,7,10tetraoxa-cyclododec-2-ylmethoxymethyl)-benzoic acid tert-butyl ester

Guidance literature:: With sodium hydride; In tetrahydrofuran; at 20 ℃; for 5h;
DOI:10.1016/j.tet.2005.06.093

Reference yield:

: 118-90-1
ortho-methylbenzoic acid

: 864851-88-7
2-(1,4,7,10tetraoxa-cyclododec-2-ylmethoxymethyl)-benzoic acid tert-butyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 100 percent / oxalyl chloride / benzene / 14 h / 20 °C

2: 85 percent / pyridine / 20 °C

3: 61 percent / N-bromosuccinimide; benzoyl peroxide / CCl₄ / 2 h / Irradiation

4: 68 percent / sodium hydride / tetrahydrofuran / 5 h / 20 °C

With pyridine; N-Bromosuccinimide; oxalyl dichloride; sodium hydride; dibenzoyl peroxide; In tetrahydrofuran; tetrachloromethane; benzene;
DOI:10.1016/j.tet.2005.06.093

Reference yield:

: 16537-18-1
tert-butyl 2-methylbenzoate

: 864851-88-7
2-(1,4,7,10tetraoxa-cyclododec-2-ylmethoxymethyl)-benzoic acid tert-butyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 61 percent / N-bromosuccinimide; benzoyl peroxide / CCl₄ / 2 h / Irradiation

2: 68 percent / sodium hydride / tetrahydrofuran / 5 h / 20 °C

With N-Bromosuccinimide; sodium hydride; dibenzoyl peroxide; In tetrahydrofuran; tetrachloromethane;
DOI:10.1016/j.tet.2005.06.093