5-(adamant-1-yl)-4-(tert-butyldimethylsilyloxy)-2-methylphenylboronic acid

Base Information

Chemical Name:5-(adamant-1-yl)-4-(tert-butyldimethylsilyloxy)-2-methylphenylboronic acid
CAS No.:1160658-12-7
Molecular Formula:C₂₃H₃₇BO₃Si
Molecular Weight:400.441
Hs Code.:

Synonyms:5-(adamant-1-yl)-4-(tert-butyldimethylsilyloxy)-2-methylphenylboronic acid

Suppliers and Price of 5-(adamant-1-yl)-4-(tert-butyldimethylsilyloxy)-2-methylphenylboronic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 5-(adamant-1-yl)-4-(tert-butyldimethylsilyloxy)-2-methylphenylboronic acid

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 5-(adamant-1-yl)-4-(tert-butyldimethylsilyloxy)-2-methylphenylboronic acid

There total 1 articles about 5-(adamant-1-yl)-4-(tert-butyldimethylsilyloxy)-2-methylphenylboronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 1160658-11-6
2-(adamant-1-yl)-(4-bromo-5-methylphenyl) tert-butyldimethylsilyl ether

: 1160658-12-7
5-(adamant-1-yl)-4-(tert-butyldimethylsilyloxy)-2-methylphenylboronic acid

Guidance literature:: 2-(adamant-1-yl)-(4-bromo-5-methylphenyl) tert-butyldimethylsilyl ether; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 0.666667h; Inert atmosphere;

With Triisopropyl borate; at -78 - 25 ℃;

With hydrogenchloride; water; at 0 ℃;
DOI:10.1016/j.ejmech.2009.01.011

Reference yield: 78.0%

: 496856-44-1
methyl 2-(3-chloro-4-(triuoromethylsulfonyloxy)phenyl)acetate

: 1160658-12-7
5-(adamant-1-yl)-4-(tert-butyldimethylsilyloxy)-2-methylphenylboronic acid

: 1160658-13-8
methyl 2-[5'-(adamant-1-yl)-4'-(tert-butyldimethylsilyloxy)-2-chloro-2'-methylbiphenyl-4-yl]acetate

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; triethylamine; In N,N-dimethyl-formamide; at 90 ℃; for 23h; Inert atmosphere;
DOI:10.1016/j.ejmech.2009.01.011

Reference yield: 67.0%

: 524937-24-4
(E)-ethyl 3-(3-chloro-4-(trifluoromethylsulphonyloxy)phenyl)acrylate

: 1160658-12-7
5-(adamant-1-yl)-4-(tert-butyldimethylsilyloxy)-2-methylphenylboronic acid

: 1160658-23-0
(E)-ethyl 3-[5'-(adamant-1-yl)-4'-(tert-butyldimethylsilyloxy)-2-chloro-2'-methylbiphenyl-4-yl]acrylate

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate; lithium chloride; In N,N-dimethyl-formamide; at 80 ℃; for 22h; Inert atmosphere;
DOI:10.1016/j.ejmech.2009.01.011