Technology Process of (meso-α-5,10,15,20-tetrakis(2-[3,3',3'',3'''-(N,N,N',N''-tris(2-aminoethyl)amino)-(N'-2-hydroxy-5-nitro-benzyl)tetrapropionylamino]phenyl)porphyrinato)iron(II)
There total 1 articles about (meso-α-5,10,15,20-tetrakis(2-[3,3',3'',3'''-(N,N,N',N''-tris(2-aminoethyl)amino)-(N'-2-hydroxy-5-nitro-benzyl)tetrapropionylamino]phenyl)porphyrinato)iron(II) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
triethylamine;
In
tetrahydrofuran;
under Ar atm. soln. Fe complex, 2-bromomethyl-4-nitrophenol and Et3N in THF was heated at 65°C overnight; soln. was dried in vacuo, residue was dissolved in CHCl3, washed with HCl, neutralized with satd. NaHCO3, dried over MgSO4, filtered and evapd.;chromy. on silica (MeOH-CHCl3);
DOI:10.1021/ic0514703
